Dehydration process and structural development of cordierite ceramic precursors derived from FTIR spectroscopic investigations

2002 ◽  
Vol 29 (8) ◽  
pp. 545-551 ◽  
Author(s):  
D. Voll ◽  
A. Beran
Author(s):  
T.R. Dinger ◽  
G. Thomas

The use of Si3N4, alloys for high temperature, high stress structural applications has prompted numerous studies of the oxynitride glasses which exist as intergranular phases in their microstructures. Oxynitride glasses have been investigated recently in their bulk form in order to understand their crystallization behavior for subsequent Si3N4 applications and to investigate their worth as glass-ceramic precursors. This research investigates the crystallization sequence of a glass having a normalized composition of Y26Si30Al11 ON11 and lying in the A1N-Y2O3-SiO2 section of the Y-Si-Al-O-N system. Such glasses exist as intergranular phases in the technologically important Y2O3/Al2O3-fluxed Si3N4 alloys.


Author(s):  
J.M. Schwartz ◽  
L.F. Francis ◽  
L.D. Schmidt ◽  
P.S. Schabes-Retchkiman

Ceramic thin films and coatings are of interest for electrical, optical, magnetic and thermal barrier applications. Critical for improved properties in thin films is the development of specific microstructures during processing. To this end, the sol-gel method is advantageous as a versatile processing route. The sol-gel process involves depositing a solution containing metalorganic or colloidal ceramic precursors onto a substrate and heating the deposited layer to form a crystalline or non-crystalline ceramic coating. This route has several advantages, including the ability to create tailored microstructures and properties, to coat large or small areas, simple or complex shapes, and to more easily prepare multicomponent ceramics. Sol-gel derived coatings are amorphous in the as-deposited state and develop their crystalline structure and microstructure during heat-treatment. We are particularly interested in studying the amorphous to crystalline transformation, because many key features of the microstructure such as grain size and grain size distribution may be linked to this transformation.


2005 ◽  
Vol 125 ◽  
pp. 177-180
Author(s):  
T. Lopez ◽  
M. Picquart ◽  
G. Aguirre ◽  
Y. Freile ◽  
D. H. Aguilar ◽  
...  

1976 ◽  
Vol 37 (C6) ◽  
pp. C6-463-C6-470 ◽  
Author(s):  
A. TRAUTWEIN ◽  
R. RESCHKE ◽  
I. DÉZSI ◽  
F. E. HARRIS

1992 ◽  
Author(s):  
MICHAEL LOU ◽  
WALTER TSUHA ◽  
PAUL LARKIN

Author(s):  
Henrik Rasmussen ◽  
Paul Martin Holm

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Rasmussen, H., & Holm, P. M. (1999). Proterozoic thermal activity in the Archaean basement of the Disko Bugt region and eastern Nuussuaq, West Greenland: evidence from K-Ar and 40Ar-39Ar mineral age investigations. Geology of Greenland Survey Bulletin, 181, 55-64. https://doi.org/10.34194/ggub.v181.5113 _______________ K-Ar and 40Ar-39Ar analyses of amphiboles from Archaean amphibolites and gneisses show that Proterozoic tectono-thermal activity has played an important role in the metamorphic and structural development of the Precambrian rocks around north-eastern Disko Bugt and in eastern Nuussuaq. Proterozoic thermal activity lead to resetting of the K-Ar ages of amphiboles in eastern Nuussuaq, resulting in ages of c. 1750 to 1925 Ma; in the Disko Bugt area the effects are seen in total or partial resetting with K-Ar ages scattering mostly between 2750 and 1870 Ma. Resetting is caused either by total diffusion of earlier accumulated radiogenic argon or by complete recrystallisation of the amphiboles. Archaean 40Ar-39Ar ages obtained from mafic xenoliths within the Atâ tonalite show that not all parts of the area suffered argon loss during Proterozoic reheating. Incorporation of significant proportions of excess argon in some amphiboles is seen from 40Ar-39Ar mineral age spectra obtained for samples from supracrustal rocks and from mafic xenoliths in the Atâ tonalite. Phlogopite phenocrysts from a lamproite stock yielded a K-Ar age of 1764 ± 24 Ma, identical to a previously determined K-Ar age of the matrix phlogopite. These ages probably date the emplacement of the lamproite, and mark the time after which no tectono-thermal events affected the area.


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