Influence of carbonate ions on the micellization behavior in triblock copolymer solution

2002 ◽  
Vol 74 (0) ◽  
pp. s525-s527 ◽  
Author(s):  
P. Thiyagarajan ◽  
L. Fan





2007 ◽  
Vol 64 (5) ◽  
pp. 309-316
Author(s):  
Katsuhiro INOMATA ◽  
Ai BANNO ◽  
Eijiro SATO ◽  
Hideki SUGIMOTO ◽  
Eiji NAKANISHI


2004 ◽  
Vol 76 (1) ◽  
pp. 123-131 ◽  
Author(s):  
I. C. Riegel ◽  
F. M. de Bittencourt ◽  
O. Terrau ◽  
A. Eisenberg ◽  
C. L. Petzhold ◽  
...  

Solution properties of a highly asymmetric aminofunctionalized triblock copolymer of 5-(N,N-diethylamino)isoprene and styrene were investigated in dilute regime. Toluene, THF, 1,4-dioxane, or DMF were used to prepare the solutions. It was found that the solvent selectivity for one or both block affects the copolymer solution behavior as reflected by the calculated parameters through light-scattering techniques: weight-averaged, molecular-weight, radius of gyration, translational diffusion coefficient, and hydrodynamic radius. According to what was determined, the quality of the polymer-solvent interactions decreases in the order: toluene, THF, 1,4-dioxane, and DMF. After quaternization with dimethyl sulfate, the triblock copolymer consisted of a polystyrene (PS) block with short poly[5-(N,N,N-diethylmethylammonium)isoprene][methyl sulfate] block at both chain ends, shows a better solvation in polar solvents. Transmission electron microscopy (TEM) was used to characterize the crew-cut aggregates prepared from the quaternized copolymer.



Langmuir ◽  
2005 ◽  
Vol 21 (16) ◽  
pp. 7533-7539 ◽  
Author(s):  
Zhibin Li ◽  
Zhiyun Chen ◽  
Honggang Cui ◽  
Kelly Hales ◽  
Kai Qi ◽  
...  


2009 ◽  
Vol 54 (11) ◽  
pp. 1912-1917 ◽  
Author(s):  
JingYi Rao ◽  
ZhiYuan Zhu ◽  
ShiYong Liu


1998 ◽  
Vol 58 (4) ◽  
pp. R4084-R4087 ◽  
Author(s):  
T. M. Slawecki ◽  
C. J. Glinka ◽  
B. Hammouda


RSC Advances ◽  
2015 ◽  
Vol 5 (31) ◽  
pp. 24231-24238 ◽  
Author(s):  
Tongming Sun ◽  
Jinli Zhu ◽  
Miao Wang ◽  
Minlei Lu ◽  
Jinjin Ding ◽  
...  

A new glucosyl triblock PGNA copolymer was first synthesized and the aqueous PGNA copolymer solution exhibits good sol–gel phase transition behaviours. The formed hydrogels are sensitive to the temperature and pH.



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