Molecular interactions and functionalities of organic additive in a perovskite semiconducting device: a case study towards high performance solar cells

A chiral aromatic amino acid, (S)-3-Amino-4-phenylbutyric acid hydrochloride (s-APACl), was employed as an additive to the active layer in a p-i-n organic-inorganic halide perovskite solar cell. This additive led to...

Shifts in preference for Natural American Spirit and associated belief that one’s own cigarette brand might be less harmful than other brands: results from Waves 1–4 of the Population Assessment of Tobacco and Health (PATH) Study (2013–2018)

IntroductionPeople believe that cigarettes using ‘organic,’ ‘additive-free’ or similar descriptors are less harmful than other cigarettes. Natural American Spirit (NAS) is the most popular US cigarette brand using these descriptors. This cohort study describes changes in US smokers’ odds of preferring NAS and changes in NAS smokers’ odds of believing their brand might be less harmful than other brands.MethodsData come from four waves (2013–2018) of the Population Assessment of Tobacco and Health (PATH) Study. Generalised estimating equations produced population-averaged estimates of relationships between (1) NAS brand preference and wave and (2) belief that one’s own brand might be less harmful than other brands, wave and NAS brand preference. Models tested interactions by age group and sexual minority status.ResultsThe odds that smokers preferred NAS increased by 60% in W4 relative to W1. Disproportionate preference by younger adult and sexual minority smokers was observed. The odds that NAS smokers believed their own brand might be less harmful decreased by 50% between W1 and W4, but this perception was still 16 times higher for NAS compared with non-NAS smokers. Given the increasing preference for NAS, there was no significant change in the absolute number of NAS smokers who believed their own brand might be less harmful (W1: 562 122 (95% CI 435 190 to 689 055) vs W4: 580 378 (95% CI 441 069 to 719 689)).ConclusionsBoth brand popularity and concentration of brand-related harm perceptions are important for understanding population impact of changes in cigarette marketing.

Mechanical characteristics of bacterial cellulose-reinforced mycelium composite materials

Background While mycelium is considered a promising alternative for fossil-based resins in lignocellulosic materials, the mechanical properties of mycelium composite materials remain suboptimal, among other reasons due to the weak internal bonds between the hyphae and the natural fibres. A solution could be provided by the hybridisation of mycelium materials with organic additives. More specifically, bacterial cellulose seems to be a promising additive that could result in reinforcing mycelium composites; however, this strategy is underreported in scientific literature. Results In this study, we set out to investigate the mechanical properties of mycelium composites, produced with the white-rot fungus Trametes versicolor, and supplemented with bacterial cellulose as an organic additive. A methodological framework is developed for the facile production of bacterial cellulose and subsequent fabrication of mycelium composite particle boards based on a hybrid substrate consisting of bacterial cellulose and hemp in combination with a heat-pressing approach. We found that, upon adding bacterial cellulose, the internal bond of the composite particle boards significantly improved. Conclusions The addition of bacterial cellulose to mycelium composite materials not only results in a strengthening of internal bonding of mycelium material, but also renders tuneable mechanical properties to the material. As such, this study contributes to the ongoing development of fully biological hybrid materials with performant mechanical characteristics.

Environmental Impact Assessment of Different Warm Mix Asphalts

Within the last decade, much attention has been focused on determining viable techniques for producing sustainable asphalt mixtures and minimizing fuel use and greenhouse gas emissions. Thus, warm mix asphalt (WMA) has become a topic of significant interest among road specialists as it offers a potential solution for reducing the environmental impact of the asphalt mixtures due to the decreased temperatures they require for mixing and compaction compared to hot mix asphalt (HMA). The present study is focused on the Life Cycle Assessment (LCA), according to a “Cradle-to-Gate” approach, of hot mix asphalt and warm mix asphalt prepared with locally available materials and different warm mix additives such as organic additives, chemical additive, and synthetic zeolite. For the analysis of the environmental impact of the warm mix asphalts was used a dedicated software for modeling and evaluating the LCA. The WMA prepared with chemical additive or organic additive led to a decrease of the environmental impact, in the production phase, compared to HMA. The study reveals that the raw materials extraction has the greatest impact on the environment in all studied cases, followed by the actual production phase of the asphalt mixture. For WMA produced with additives there was a decrease in the global impact on the environment compared to HMA.

Functioned catalysts with magnetic core applied in the ibuprofen degradation

In the present work, the performance of Ag/ZnO/CoFe2O4 magnetic photocatalysts in the photocatalytic degradation of Ibuprofen (IBP) was evaluated. This study considered the use of pure Ag/ZnO (5% Ag) and also use the Ag/ZnO/CoFe2O4 magnetic catalysts containing different amounts (5, 10 and 15% wt) of cobalt ferrite (CoFe2O4). The catalysts were characterized by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and photoacoustic Spectroscopy. To carried the photocatalytic degradation reaction, different concentrations of the ibuprofen contaminant solution (10, 20 and 30 ppm) and different concentrations of photocatalyst were tested (0.3 gL−1, 0.5 gL−1 and 1.0 gL−1). The reaction parameters studied were: IBP concentration, catalyst concentration, adsorption and photolysis, influence of the matrix, radiation source (solar and artificial) and the effect of organic additive. At the end of the photocatalytic tests, the best operation conditions were defined. Considering the obtained results of degradation efficiency and magnetic separation, the optimal parameters selected to proceed with the other tests of the study were: ibuprofen solution concentration 10 ppm, Ag/ZnO/CoFe2O4(5%) catalyst at a concentration of 0.3 g L−1 and pH 4.5 of the reaction medium. The results indicated the feasibility of magnetic separation of the synthesized catalysts. A long duration test indicated that the catalyst exhibits stability throughout the degradation reaction, as more than 80% of ibuprofen was degraded after 300 minutes. The photocatalytic activity was directly affected by the ferrite load. The higher the nominal load of ferrite, the lower the performance in ibuprofen degrading. It was also observed that the smallest amount of ferrite studied was enough for the catalyst to be recovered and reused. The adsorption and photolysis tests did not show significant results in the IBP degradation. In addition, it was possible to verify that the aqueous matrix, the use of solar radiation and the addition of additive (acid formic) interfered direct in the process. The catalyst reuse tests indicated that it can be recovered and reused at least three times without considerable catalytic activity loss.

Detection of Organic Additives in Copper Plating Bath Using Voltammetric Methods That Involve a Screen-printed Nano-Au Electrode

Three electrochemical methods used to detect organic additives, A, B and C, in acidic plating baths. Cyclic voltammetric stripping (CVS) is used in industry to detect the concentration of organic additives indirectly by measuring the effect of commercial organic additives on the rate of copper deposition. This study directly determines the concentration of organic additives on a screen-printed nano-Au electrode at high potential using three different electrochemical methods: linear scanning voltammetry (LSV), differential pulse voltammetry (DPV) and square wave voltammetry (SWV). The results show that the response currents for the three electrochemical methods exhibit a linear relationship with the concentration of organic additives. The nano-Au electrode is the most sensitive device for the detection of organic additive B using LSV.

Characterization of Sustainable Asphalt Mixtures Containing High Reclaimed Asphalt and Steel Slag

Policymakers are implementing the transition to a circular model in all economic sectors to drastically mitigate the effects of climate change. In this regard, the producers of paving products should promote the reuse and recycling of solid waste in the design of sustainable asphalt materials. This study evaluated the performance-based properties of three highly recycled mixtures for wearing courses of asphalt pavements containing steel slag and varying amounts (25, 40, and 50%) of fractionated reclaimed asphalt (RA). In addition, the mixtures incorporated a warm mix asphalt (WMA) organic additive to lower production temperatures compared to a reference hot mix asphalt (HMA). Based on the experimental results, the warm recycled asphalt mixtures show equivalent or better performance compared to HMA in terms of moisture susceptibility, stiffness, rutting and fracture resistance, and surface macrotexture. Therefore, the combined incorporation of RA and steel slag with WMA was proven to be an effective option in designing environmentally friendly and high-performance wearing course mixtures.

Organic additive release from plastic to seawater is lower under deep-sea conditions

Plastic garbage patches at the ocean surface are symptomatic of a wider pollution affecting the whole marine environment. Sinking of plastic debris increasingly appears to be an important process in the global fate of plastic in the ocean. However, there is insufficient knowledge about the processes affecting plastic distributions and degradation and how this influences the release of additives under varying environmental conditions, especially in deep-sea environments. Here we show that in abiotic conditions increasing hydrostatic pressure inhibits the leaching of the heaviest organic additives such as tris(2-ethylhexyl) phosphate and diisononyl phthalate from polyethylene and polyvinylchloride materials, whereas deep-sea and surface marine prokaryotes promote the release of all targeted additives (phthalates, bisphenols, organophosphate esters). This study provides empirical evidences for more efficient additive release at the ocean surface than in deep seawater, where the major plastic burden is supposed to transit through before reaching the sediment compartment.