The outcomes of successive droplets impacting onto solid surface of the steam separator in a nuclear power system’s steam generator has a strong effect on the separating efficiency. Due to amounts of influencing factors, experimental research is an important method to study the phenomena of droplet-wall collision. However, because it is hard to generator continuous droplets with controllable uniform size and frequency, experimental studies about successive droplets impacting on solid surface are relative limited. In this study, a novel drop-on-demand (DOD) droplet generator is designed and fabricated based on piezoelectric ceramics, in which successive droplets with a uniform diameter can be generated. Firstly, the structure design of the DOD droplet generator, the setup of the control system and working principle are described in detail in this paper. Then the droplet generating performance of the device under different signal frequency fs, signal amplitude U, duty ratio Dr, and nozzle diameter Dn are investigated experimentally using a high-speed camera at 4000 fps. Finally, the influence of the signal frequency fs, voltage U, duty ratio Dr and nozzle diameter Dn on the diameter of droplet Dd is discussed. A test of successive droplets generated by the device impacting on an aluminum plate is conducted.