Molecular theory considering nuclear potential wells

2021 ◽  
Vol 27 (6) ◽  
Author(s):  
Dariush Habibollah Zadeh
2021 ◽  
Author(s):  
Dariush Habibollah Zadeh

Abstract This article introduces potential wells around nuclei and their roles in chemical bonds. The approach uses one-electron Bohr atomic model concept. Multi-electron atoms are converted to one-electron atoms by grounding all inactive, non-reacting electrons using the Apparent Nuclear Charge (ANC) and Electron Shielding Effect (ESE) concepts introduced in earlier publications. Then the resulting two one-electron atoms and their potential wells are utilized to obtain the related chemical bond length. The methodology is applicable to all elements of periodic table without a need for any additional tool. To test the concept, calculated bond lengths were compared to experimental ones for about 90 different bonds which showed an average error of less than 5%. The article discusses some nontraditional views for chemical bonds which may contradict the traditional beliefs in chemistry. Hopefully, readers would consider the calculated results in support of the presented views. Attached to this article is a computer software program which was prepared with sample input and output files for readers. The software can be utilized to obtain any interested bond length. The software is applicable to all elements in the periodic table up to the element Hassium with the atomic number of 108.


1998 ◽  
Vol 13 (17) ◽  
pp. 1383-1392 ◽  
Author(s):  
F. V. DE BLASIO ◽  
G. LAZZARI

In the inner crust of a neutron star, the superfluid neutron liquid shares a fraction of the volume with neutron-rich nuclei and thus cannot be considered as uniform. We find that quasi-resonant states, due to elastic scattering with the effective nuclear potential wells, can enhance the neutron density of states at the Fermi surface for some values of the energy of the incident neutron. This may locally change the pairing energy gap of the superfluid neutrons up to a factor of three to four. We then discuss the smoother change of the neutron effective matrix element induced by the presence of the nuclei considering the case in which the superfluid coherence length is larger than the nuclear sizes. The results show that the value of the pairing gap as calculated for infinite systems is not directly the one that should be expected to exist in the crust of a neutron star and we work out an approximate formula for the gap taking into account both effects. The sudden change of the neutronic superfluid gap in localized crust shells due to the nuclear quasi-resonant states can have consequences for theories of the rotational and thermal evolution of neutron stars while the smooth, continuous variation of the effective matrix element can have implications for the cooling of the star.


2014 ◽  
Vol 378 (22-23) ◽  
pp. 1593-1597 ◽  
Author(s):  
O.L. de Lange ◽  
R.E. Raab
Keyword(s):  

2021 ◽  
Vol 502 (2) ◽  
pp. 1785-1796
Author(s):  
R A Jackson ◽  
S Kaviraj ◽  
G Martin ◽  
J E G Devriendt ◽  
A Slyz ◽  
...  

ABSTRACT In the standard ΛCDM (Lambda cold dark matter) paradigm, dwarf galaxies are expected to be dark matter-rich, as baryonic feedback is thought to quickly drive gas out of their shallow potential wells and quench star formation at early epochs. Recent observations of local dwarfs with extremely low dark matter content appear to contradict this picture, potentially bringing the validity of the standard model into question. We use NewHorizon, a high-resolution cosmological simulation, to demonstrate that sustained stripping of dark matter, in tidal interactions between a massive galaxy and a dwarf satellite, naturally produces dwarfs that are dark matter-deficient, even though their initial dark matter fractions are normal. The process of dark matter stripping is responsible for the large scatter in the halo-to-stellar mass relation in the dwarf regime. The degree of stripping is driven by the closeness of the orbit of the dwarf around its massive companion and, in extreme cases, produces dwarfs with halo-to-stellar mass ratios as low as unity, consistent with the findings of recent observational studies. ∼30 per cent of dwarfs show some deviation from normal dark matter fractions due to dark matter stripping, with 10 per cent showing high levels of dark matter deficiency (Mhalo/M⋆ < 10). Given their close orbits, a significant fraction of dark matter-deficient dwarfs merge with their massive companions (e.g. ∼70 per cent merge over time-scales of ∼3.5 Gyr), with the dark matter-deficient population being constantly replenished by new interactions between dwarfs and massive companions. The creation of these galaxies is therefore a natural by-product of galaxy evolution and their existence is not in tension with the standard paradigm.


1994 ◽  
Vol 266 (3) ◽  
pp. F367-F374 ◽  
Author(s):  
R. Rick

The pH of the isolated frog skin epithelium was determined on a cellular and subcellular level based on the distribution of a weak organic acid, 4-bromobenzoic acid. The indicator is detectable by X-ray microanalysis due to the presence of an element label. The results show that the pH of principal cells, but not the Na concentration, is closely correlated with the rate of transepithelial Na transport. Acidification leads to an inhibition of Na transport, regardless of whether the change was spontaneous or experimentally induced. Under the conditions of this study, the pH of principal cells was not well regulated. At a bath pH of 7.0, large pH differences between the cell layers were detectable. In mitochondria-rich cells, the pH was a function of the intracellular Cl concentration but not the Na transport rate. The cytoplasmic pH consistently exceeded the nuclear pH. The nuclear-cytoplasmic pH differential in principal cells amounted to 0.3 pH units, which is equivalent to a nuclear potential of -17 mV. The results support the view that the intracellular pH (pHi) is an important regulator of transepithelial Na transport. Regulation is primarily achieved at the level of the apical Na channel, making the Na influx the rate-limiting step in Na reabsorption.


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