Application of the Kramers–Kronig relationships in the electrochemical impedance models fit

2021 ◽  
Author(s):  
Junhua Luo ◽  
Xinghua Liang ◽  
Yuhao Zhang ◽  
Chenghua Liang ◽  
Hassan Yassine ◽  
...  
Keyword(s):  
Electrochemical Impedance ◽  
Impedance Models

Review on Physical Impedance Models in Modern Battery Research

2021 ◽  
Author(s):  
Rohit Gaddam ◽  
Leon Katzenmeier ◽  
Xaver Lamprecht ◽  
Aliaksandr Bandarenka
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Complex Processes ◽  
Versatile Tool ◽  
Impedance Models

Electrochemical impedance spectroscopy (EIS) is a versatile tool to understand complex processes in batteries. This technique can investigate the effects of the battery components like the electrode and electrolyte, electrochemical...

scholarly journals Time domain diffusion parameters identification of electrochemical impedance models using fractional order system

2018 ◽  
Vol 51 (15) ◽  
pp. 377-382 ◽  
Author(s):  
Achraf Nasser Eddine ◽  
Benoît Huard ◽  
Jean-Denis Gabano ◽  
Thierry Poinot ◽  
Anthony Thomas ◽  
...  
Keyword(s):  
Fractional Order ◽  
Time Domain ◽  
Electrochemical Impedance ◽  
Parameters Identification ◽  
Fractional Order System ◽  
Order System ◽  
Diffusion Parameters ◽  
Impedance Models

Electrochemical impedance models for molten salt corrosion

2001 ◽  
Vol 43 (4) ◽  
pp. 787-801 ◽  
Author(s):  
C.L Zeng ◽  
W Wang ◽  
W.T Wu
Keyword(s):  
Molten Salt ◽  
Electrochemical Impedance ◽  
Salt Corrosion ◽  
Impedance Models

scholarly journals Time-domain fitting of battery electrochemical impedance models

2015 ◽  
Vol 288 ◽  
pp. 345-352 ◽  
Author(s):  
S.M.M. Alavi ◽  
C.R. Birkl ◽  
D.A. Howey
Keyword(s):  
Time Domain ◽  
Electrochemical Impedance ◽  
Impedance Models

EIS study of the corrosion behavior of an organic coating applied on Algerian oil tanker

2020 ◽  
Vol 117 (6) ◽  
pp. 610
Author(s):  
Nadia Hammouda ◽  
Kamel Belmokre
Keyword(s):  
Corrosion Protection ◽  
Electrochemical Impedance ◽  
Paint Film ◽  
Organic Coating ◽  
Diffusion Resistance ◽  
Double Layer Capacitance ◽  
Carbon Steel Surface ◽  
Chloride Environment ◽  
Oil Tanker ◽  
Epoxy Paint

Organic coatings are widely employed in the corrosion protection of most metal surfaces, particularly steel. They provide a barrier against corrosive species present in the environment, due to their high resistance to oxygen, water and ions transport. This study focuses on the evaluation of corrosion protection performance of epoxy paint on the carbon steel surface in chloride environment (3% NaCl) by Electrochemical Impedance Spectroscopy (EIS). The electrochemical behavior of painted surface was estimated by EIS parameters that contained paint film resistance, paint film capacitance and double layer capacitance. On the basis of calculation using EIS spectrums it was observed that pore resistance (Rpore) decreased with the appearance of doubled layer capacitance (Cdl) due to the electrolyte penetration through the film. This was further confirmed by the decrease of diffusion resistance (Rd) which was also the indicator of the deterioration of paint film protectiveness. Microscopic analyses have shown that oxidation dominates the corroded surfaces.

Experimental and Theoretical Comparable Study of Pure and Zinc Porphyrin Surface Modified ZnO Nanorod Arrays for Hybrid Solar Cell Applications

2020 ◽  
pp. 114-119
Keyword(s):  
Solar Cell ◽  
Electrochemical Impedance ◽  
Hybrid Solar Cell ◽  
Cell Performance ◽  
Solar Cell Performance ◽  
Solar Cell Efficiency ◽  
Cell Efficiency ◽  
Annealing Effects ◽  
Vertically Aligned ◽  
Surface Modified

Experimental and theoretical study Porphyrin-grafted ZnO nanowire arrays were investigated for organic/inorganic hybrid solar cell applications. Two types of porphyrin – Tetra (4-carboxyphenyle) TCPP and meso-Tetraphenylporphine (Zinc-TPP)were used to modify the nanowire surfaces. The vertically aligned nanowires with porphyrin modifications were embedded in graphene-enriched poly (3-hexylthiophene) [G-P3HT] for p-n junction nanowire solar cells. Surface grafting of ZnO nanowires was found to improve the solar cell efficiency. There are different effect for the two types of porphyrin as results of Zn existing. Annealing effects on the solar cell performance were investigated by heating the devices up to 225 °C in air. It was found that the cell performance was significantly degraded after annealing. The degradation was attributed to the polymer structural change at high temperature as evidenced by electrochemical impedance spectroscopy measurements.

On the Properties of an Ion Conductive System Incorporated in Hybrid Films

2000 ◽  
Vol 628 ◽  
Author(s):  
G. González ◽  
P. J. Retuert ◽  
S. Fuentes
Keyword(s):  
Electrochemical Impedance ◽  
Ternary Phase Diagram ◽  
Lithium Perchlorate ◽  
Molar Ratio ◽  
Ionic Conductors ◽  
X Ray Diffraction ◽  
Poly Ethylene Oxide ◽  
Ion Conducting ◽  
Poly Ethylene ◽  
High Degree

ABSTRACTBlending the biopolymer chitosan (CHI) with poly (aminopropilsiloxane) oligomers (pAPS), and poly (ethylene oxide) (PEO) in the presence of lithium perchlorate lead to ion conducting products whose conductivity depends on the composition of the mixture. A ternary phase diagram for mixtures containing 0.2 M LiClO4 shows a zone in which the physical properties of the products - transparent, flexible, mechanically robust films - indicate a high degree of molecular compatibilization of the components. Comparison of these films with binary CHI-pAPS nanocomposites as well as the microscopic aspect, thermal behavior, and X-ray diffraction pattern of the product with the composition PEO/CHI/pAPS/LiClO4 1:0.5:0.6:0.2 molar ratio indicates that these films may be described as a layered nanocomposite. In this composite, lithium species coordinated by PEO and pAPS should be inserted into chitosan layers. Electrochemical impedance spectroscopy measurements indicate the films are pure ionic conductors with a maximal bulk conductivity of 1.7*10-5 Scm-1 at 40 °C and a sample-electrode interface capacitance of about 1.2*10-9 F.

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