Investigation of CO Oxidation Transient Kinetics on an Oxygen Pre-covered Au(211) Stepped Surface

2008 ◽  
Vol 128 (3-4) ◽  
pp. 263-267 ◽  
Author(s):  
Enrique Samano ◽  
Jooho Kim ◽  
Bruce E. Koel
Author(s):  
Kyriaki Polychronopoulou ◽  
Ayesha A. AlKhoori ◽  
Angelos M. Efstathiou ◽  
Maguy Abi Jaoude ◽  
C. M. Damaskinos ◽  
...  

1994 ◽  
Vol 49 (24) ◽  
pp. 4375-4390 ◽  
Author(s):  
F.H.M. Dekker ◽  
G. Klopper ◽  
A. Bliek ◽  
F. Kapteijn ◽  
J.A. Moulijn

1997 ◽  
Vol 04 (06) ◽  
pp. 1359-1363 ◽  
Author(s):  
H. UETSUKA ◽  
K. WATANABE ◽  
H. OHNUMA ◽  
K. KUNIMORI

Infrared-chemiluminescence spectra of CO 2 molecules formed by steady-state CO oxidation on Pd (111), Pd (110), Pd (100) and polycrystalline- Pd surfaces have been measured to get information on the surface reaction dynamics. In all cases, the product CO 2 was vibrationally and rotationally excited. The CO 2 molecules desorbed from Pd (100) and Pd (111), which have flat surfaces, were vibrationally more excited than those from Pd (110) (stepped surface) and polycrystalline Pd . These results show that the dynamics of CO oxidation on Pd surfaces are structure-sensitive, i.e. the structure of the activated CO 2 complex depends on the surface structures of the reaction sites. Furthermore, the activities of steady-state CO oxidation as a function of surface temperature were different among these Pd surfaces, which indicates that the CO oxidation on Pd is also structure-sensitive in the kinetics.


1996 ◽  
Vol 100 (3) ◽  
pp. 1048-1054 ◽  
Author(s):  
Tsuyoshi Sueyoshi ◽  
Takehiko Sasaki ◽  
Yasuhiro Iwasawa

2013 ◽  
Vol 133 (12) ◽  
pp. 642-647 ◽  
Author(s):  
Hitomi Kawakami ◽  
Akinori Zukeran ◽  
Koji Yasumoto ◽  
Yoshiyasu Ehara ◽  
Toshiaki Yamamoto

2004 ◽  
Vol 40 (1) ◽  
pp. 8
Author(s):  
N. Dzyuban ◽  
E. S. Bikbulatov ◽  
E. M. Bikbulatova ◽  
I. A. Kuznetsova

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