Photochemical Preparation of Anatase Titania Supported Gold Catalyst for Ethanol Synthesis from CO2 Hydrogenation

2017 ◽  
Vol 148 (1) ◽  
pp. 11-22 ◽  
Author(s):  
Dong Wang ◽  
Qingyuan Bi ◽  
Guoheng Yin ◽  
Peng Wang ◽  
Fuqiang Huang ◽  
...  
2018 ◽  
Vol 130 (27) ◽  
pp. 8367-8371 ◽  
Author(s):  
Minjune Kim ◽  
Yaqiong Su ◽  
Atsushi Fukuoka ◽  
Emiel J. M. Hensen ◽  
Kiyotaka Nakajima

1998 ◽  
Vol 14 (09) ◽  
pp. 769-771
Author(s):  
Fu Jin-Kun ◽  
◽  
Liu Yue-Ying ◽  
Hu Rong-Zong ◽  
Zeng Jin-Long ◽  
...  

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Shaofeng Liu ◽  
Wei Xu ◽  
Yiming Niu ◽  
Bingsen Zhang ◽  
Lirong Zheng ◽  
...  

AbstractSupported gold catalysts play a crucial role in the chemical industry; however, their poor on-stream stability because of the sintering of the gold nanoparticles restricts their practical application. The strong metal-support interaction (SMSI), an important concept in heterogeneous catalysis, may be applied to construct the structure of catalysts and, hence, improve their reactivity and stability. Here we report an ultrastable Au nanocatalyst after calcination at 800 °C, in which Au nanoparticles are encapsulated by a permeable TiOx thin layer induced by melamine under oxidative atmosphere. Owning to the formed TiOx overlayer, the resulting Au catalyst is resistant to sintering and exhibits excellent activity and stability for catalytic CO oxidation. Furthermore, this special strategy can be extended to colloidal Au nanoparticles supported on TiO2 and commercial gold catalyst denoted as RR2Ti, providing a universal way to engineer and develop highly stable supported Au catalysts with tunable activity.


2015 ◽  
Vol 137 ◽  
pp. 164-169 ◽  
Author(s):  
Yuan-Yuan Dong ◽  
Wei-Ping Liao ◽  
Zhang-Huai Suo

2015 ◽  
Vol 641 (3-4) ◽  
pp. 694-698
Author(s):  
Jose Antonio Lopez-Sanchez ◽  
Clément Morisse ◽  
John M. Winfield ◽  
Burkhard Krumm ◽  
Thomas M. Klapötke ◽  
...  
Keyword(s):  

RSC Advances ◽  
2016 ◽  
Vol 6 (104) ◽  
pp. 102258-102263 ◽  
Author(s):  
Shujun Zhou ◽  
Xinlei Yao ◽  
Tongxiang Fan

Three-dimensional arrays of multilamellar silica nanoparticles are prepared through confined synthesis and enhance the catalytic activity of supported gold.


2007 ◽  
Vol 111 (39) ◽  
pp. 14371-14379 ◽  
Author(s):  
Sebastián E. Collins ◽  
José M. Cíes ◽  
Eloy del Río ◽  
Miguel López-Haro ◽  
Susana Trasobares ◽  
...  

2011 ◽  
Vol 236-238 ◽  
pp. 3046-3050
Author(s):  
Zhen Yu Cai ◽  
Ming Qiao Zhu ◽  
Yue Tang ◽  
Yi Liu ◽  
Huan Dai ◽  
...  

Carbon-supported gold catalysts Au/C were prepared by an impregnation-reduction method and modified by AgNO3to obtain bi-metallic catalysts Au-Ag/C, which were characterized by X-ray-diffraction (XRD) and Transmission Electron Microscope (TEM). Their catalytic performance was tested in the oxidation of cyclohexene in an autoclave without any solvent. The results showed that Ag doping can significantly enhance the catalytic performance of carbon-supported gold catalyst. Au(1.0 wt.%)-Ag(1.0 wt.%)/C has been found to be an efficient catalyst for the cyclohexene oxidation with a conversion of 27.6% at 80 °C and 0.4 MPa for 12 h while selectivity for ∑C6products (including cyclohexene oxide, 2-cyclohexene-1-ol, 2-cyclohexene-1-one and cyclohexane-1,2-diol) exceeding 88.9%, especially the selectivity of cyclohexane-1,2-diol up to 47.6%. Moreover, the effects of Au, Ag content on catalytic performance were also reported.


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