Catalytic Reduction of NOx With NH3 Over CeO2 and SiO2 Supported Tungstophosphoric Acid: Promoting Effects of Ceria Support and Cobalt Proton Substitute

2021 ◽  
Author(s):  
Imane El Arrouji ◽  
Jamil Toyir ◽  
Cherif Larabi ◽  
Kai C. Szeto ◽  
Aimery de Mallmann ◽  
...  
Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 950
Author(s):  
Imane El Arrouji ◽  
Cuirong Chen ◽  
Jamil Toyir ◽  
Cherif Larabi ◽  
Kai C. Szeto ◽  
...  

A series of HPW/CeO2 catalysts generated from 12-tungstophosphoric acid, H3PW12O40 (HPW), supported on ceria and presenting different tungsten loadings (2, 4.5, 9, 16, and 40 wt% W) were prepared and characterized by N2 physisorption, XRD, IR, Raman, and UV-Vis. The different characterization techniques suggested that low loading of tungsten resulted in mainly isolated sites, while high tungsten loading produced polymeric or tungsten clusters. Those materials exhibited high activity in NH3-SCR of NOx into N2. Moreover, the series of experiments indicated that low loading in tungsten (2% HPW/CeO2) displayed the highest activity with a remarkable N2 selectivity (99%) at medium-high temperature (300–515 °C), owing to the high amount of monomeric tungstate coverage on the catalyst surface.


2020 ◽  
Vol 10 (16) ◽  
pp. 5525-5534 ◽  
Author(s):  
Jialiang Gu ◽  
Bingjun Zhu ◽  
Rudi Duan ◽  
Yan Chen ◽  
Shaoxin Wang ◽  
...  

MnOx–FeOx-Loaded silicalite-1 catalysts exhibit high NOx conversion at low temperatures.


ChemInform ◽  
2010 ◽  
Vol 23 (29) ◽  
pp. no-no
Author(s):  
N.-Y. TOPSOEE ◽  
T. SLABIAK ◽  
B. S. CLAUSEN ◽  
T. Z. SRNAK ◽  
J. A. DUMESIC

Author(s):  
Chong Feng ◽  
Penglu Wang ◽  
Xiangyu Liu ◽  
Fuli Wang ◽  
Tingting Yan ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (67) ◽  
pp. 40948-40959
Author(s):  
Caixia Liu ◽  
Huijun Wang ◽  
Yalian Bi ◽  
Ziyin Zhang

The roles of Fe3+ and SO42− are different at low and high temperatures due to their interaction. It is the appropriate contents of Fe3+ and SO42− that can result in high NH3-SCR activity at varying temperatures.


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