Simultaneous electrochemical preparation and reduction of graphene with low oxygen content and its electrochemical properties for high-performance supercapacitors

2020 ◽  
Vol 31 (17) ◽  
pp. 14128-14136 ◽  
Author(s):  
Guoxiang Xin ◽  
Yao Zhai ◽  
Bangwen Zhang ◽  
Jinling Song ◽  
Jinhui Zhang ◽  
...  
2021 ◽  
Author(s):  
Li Zhang ◽  
Di Wang ◽  
Xian-Jin Liao ◽  
Xiao-Tao Luo ◽  
Chang-Jiu Li

Abstract Ni-Al intermetallics have excellent corrosion and oxidation resistance, but their use in thermal spraying has been limited due to issues with in-flight oxidation. In this study, a novel approach is proposed to remove oxide from Ni-Al droplets in-flight by adding a deoxidizer (diamond) to the feedstock powder. A mixture of nickel, aluminum, and diamond powders was mechanically alloyed using a combination of cryogenic and planetary ball milling. The resulting Ni/Al/diamond composite powder was then plasma sprayed via the APS process, forming Ni-Al coatings on Inconel 738 substrates. Phase composition, microstructure, porosity, and microhardness of the coatings were characterized by X-ray diffraction, scanning electron microscopy, image analysis, and hardness testing, respectively. Oxygen content measurements showed that the coatings contained significantly less oxygen than coatings made from ordinary Ni/Al powders. In-flight particle temperatures were also measured and found to be higher than 2300 °C. The low oxygen content in the coatings is attributed to the in-situ deoxidizing effect of ultrahigh temperature droplets which are also oxide-free.


1999 ◽  
Vol 577 ◽  
Author(s):  
J. Fidler ◽  
S. Sasaki ◽  
E. Estevez-Rams

ABSTRACTThe importance of newly developed permanent magnetic materials in many electro-, magnetomechanical and electronic applications can be attributed to the drastic improvement of the magnetic energy density product and coercive field. A systematic study has been undertaken in order to determine the influence of oxygen content on microstructure and coercivity of high remanence Nd2Fe14B based sintered magnets. The energy density product >400 kJ/m3 (50 MGOe) and the coercive field of 800 kA/m were obtained after a combination of rubber isostatic and transverse die pressing methods. Magnets of the composition Nd151−xFe78+xB6Cu0.03A10.7 [x= 0-2.5] were prepared using strip cast materials. The high oxygen content of the magnets was gradually decreased from values of 4000-6000 ppm to a value < 1000 ppm. Abnormal grain growth (AGG) of the 2:14:1 grains occurred preferentially in magnets with low oxygen content, thus the squareness of the demagnetisation curve drastically decreased. The oxygen content strongly affects the AGG and the magnets with higher oxygen content have the higher critical temperatures at which the AGG occurs. On the other hand, isotropic magnets tend to have the lower critical temperatures than anisotropic magnets by 10-20°C. In the second part of the paper examples of the influence of intergranular phases, grain size and grain shape observed by TEM on coercivity of sintered and melt-spun Nd-Fe-B magnets are compared.


2021 ◽  
pp. 139026
Author(s):  
Manas Ranjan Panda ◽  
Anish Raj Kathribail ◽  
Brindaban Modak ◽  
Supriya Sau ◽  
Dimple P. Dutta ◽  
...  

ChemSusChem ◽  
2017 ◽  
Vol 10 (20) ◽  
pp. 4056-4065 ◽  
Author(s):  
Shusheng Xu ◽  
Tao Wang ◽  
Yujie Ma ◽  
Wenkai Jiang ◽  
Shuai Wang ◽  
...  

2012 ◽  
Vol 727-728 ◽  
pp. 85-89
Author(s):  
Luzinete P. Barbosa ◽  
Elki C. Souza ◽  
Lucio Salgado ◽  
I. Costa

In this work, the effect of sintering atmosphere on the corrosion resistance of sintered titanium has been evaluated in 0.9 % aqueous NaCl solution to simulate physiological environment. Corrosion tests were performed on titanium porous sintered under vacuum and vacuum plus dynamic argon. The results showed better passive properties associated to the titanium sintered under argon plus vacuum atmosphere than to the vacuum sintered titanium. The better corrosion resistance of the argon plus vacuum sintered titanium was attributed to the formation of a thin passive film on the titanium surface during sintering due the low oxygen content present in this atmosphere.


1918 ◽  
Vol 27 (3) ◽  
pp. 399-412 ◽  
Author(s):  
H. G. Martin ◽  
A. S. Loevenhart ◽  
C. H. Bunting

Exposure of rabbits to an atmosphere of low oxygen content results in a stimulation of the cardiorespiratory systems, in an extension (hyperplasia) of red bone marrow and probably of a thyroid hyperplasia, with the further production of hydropic and hyaline degeneration in the cells of the parenchymatous organs. An atmosphere of high carbon dioxide and normal oxygen content produces, however, a stimulation of the cardiorespiratory systems, but no marrow extension and, in the concentrations used, but slight hydropic degeneration in the parenchyma of the glandular organs.


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