Synthesis, Structural Characterization, Hirshfeld Surface and Antioxidant Activity Analysis of a Novel Organic Cation Antimonate Complex

2017 ◽  
Vol 28 (4) ◽  
pp. 2239-2252
Author(s):  
Ikram Lahbib ◽  
Arto Valkonen ◽  
Mohamed Rzaigui ◽  
Wajda Smirani
2008 ◽  
Vol 24 (12) ◽  
pp. 1557-1562 ◽  
Author(s):  
Hironori TSUCHIYA ◽  
Takahiro UENO ◽  
Maki MIZOGAMI ◽  
Ko TAKAKURA

Author(s):  
Rayya A. Al Balushi ◽  
Muhammad S. Khan ◽  
Md. Serajul Haque Faizi ◽  
Ashanul Haque ◽  
Kieran Molloy ◽  
...  

In the crystal structure of the title compound, [Cu4Cl6O(C13H9N)4]·CH2Cl2, the core molecular structure consists of a Cu4 tetrahedron with a central interstitial O atom. Each edge of the Cu4 tetrahedron is bridged by a chlorido ligand. Each copper(II) cation is coordinated to the central O atom, two chlorido ligands and one N atom of the 4-phenylethynylpyridine ligand. In the crystal, the molecules are linked by intermolecular C—H...Cl interactions. Furthermore, C—H...π and π–π interactions also connect the molecules, forming a three-dimensional network. Hirshfeld surface analysis indicates that the most important contributions for the packing arrangement are from H...H and C...H/H...C interactions.


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