scholarly journals Synergistic Effect of Titanium Dioxide (TiO2) and Ionizing Radiation on Thermal and Mechanical Properties of Carboxymethyl Cellulose (CMC) for Potential Application in Removal of Basic Dye from Wastewater

Author(s):  
Yasser H. Gad ◽  
Hussein E. Ali ◽  
A. El-Sayed Hegazy
2021 ◽  
Author(s):  
Yasser Gad ◽  
Hussein E. Ali ◽  
El-Sayed A. Hegazy

Abstract Carboxymethyl cellulose (CMC)/titanium dioxide (TiO2) was prepared using gamma irradiation at different doses. Carboxymethyl cellulose was used as a matrix and TiO2 in different contents was added (0.25, 0.5, 1, 1.5 wt %) as a filler. The polymer composite film were irradiated at doses of 5, 10 and15 kGy using 60Co γ-ray to form crosslinked network structure. The prepared composite films were described by different diagnostic procedures including X-ray diffractometer, scanning electron microscope (SEM), FTIR as well as thermal and mechanical properties measurements. CMC/TiO2 composite films was used for removal of basic Violet 7 dye. The adsorption of the dye follows the Langmuir model a with chemical monolayer adsorption behavior. Adsorption kinetic of dyes was set up to be regular to pseudo second order kinetic model. The results showed that the prepared composite films significantly removed this basic violet 7 dye with maximum absorption capacity (123.6 mg/g).


2021 ◽  
Author(s):  
Yasser Gad ◽  
Hussein E. Ali ◽  
El-Sayed A. Hegazy

Abstract Carboxymethyl cellulose (CMC)/titanium dioxide (TiO2) was prepared using gamma irradiation at different doses. Carboxymethyl cellulose was used as a matrix and TiO2 in different contents was added (0.25, 0.5, 1, 1.5 wt %) as a filler. The polymer composite film were irradiated at doses of 5, 10 and15 kGy using 60Co γ-ray to form crosslinked network structure. The prepared composite films were described by different diagnostic procedures including X-ray diffractometer, scanning electron microscope (SEM), FTIR as well as thermal and mechanical properties measurements. CMC/TiO2 composite films was used for removal of basic Violet 7 dye. The adsorption of the dye match with the Langmuir model across chemical monolayer adsorption performance. Adsorption kinetic of dyes was set up to be regular to pseudo second order kinetic model. The results showed that the prepared composite films significantly removed this basic violet 7 dye with maximum absorption capacity (123.6 mg/g).


2011 ◽  
Vol 312-315 ◽  
pp. 513-517
Author(s):  
Leila Figueiredo de Miranda ◽  
Mauro Cesar Terence ◽  
Isabella Tereza Ferro Barbosa ◽  
Ingrid Martins Rubin ◽  
Jefferson Fernandes Alves

Hydrophilic membranes based on PVP, containing 0.4 and 1% of carboxymethylcellulose staple fibers infused with calcium alginate were obtained and characterized in this study. The main proposal of this study is related to hydrogels based on PVP modified with carboxymethyl cellulose staple fibers infused with calcium alginate. This modified hydrogel is a hydrophilic membrane with better mechanical properties that can incorporate adequate drugs into the fibers for each lesion type. The hydrogels were obtained using ionizing radiation with an electron beam, at a dose of 25 kGy. The membrane’s characterization was performed by tensile and physic-chemical tests (gel fraction and swelling). The results obtained showed that the membranes have higher mechanical strength, a higher swelling degree and a lower gel fraction.


1975 ◽  
Vol 22 (5) ◽  
pp. 173-175 ◽  
Author(s):  
Osamu Yamaguchi ◽  
Hichirô Ômaki ◽  
Kiyoshi Takeoka ◽  
Kiyoshi Shimizu

2020 ◽  
Author(s):  
Amit Kumar Sonker ◽  
Soumyendu Roy ◽  
Hanoch Daniel Wagner ◽  
Alla Zak ◽  
XiaoMeng Sui ◽  
...  

2013 ◽  
Vol 747 ◽  
pp. 157-161
Author(s):  
S. Kamthai ◽  
Rathanawan Magaraphan

According to the availability of bagasse waste and increasing environmental concern, this research is focused on the preparation of polylactic acid (PLA)/bagasse carboxymethyl cellulose (CMCB) composite in order to improve the thermal and mechanical properties of PLA/CMCB film. PLA were mixed with CMCB at different ratios (1, 2, 4 and 8%, w/w of PLA), by kneading in two roll mills and then hot pressing into film. The results revealed that the addition of CMCB had significant effects on PLA composites properties. Differential scanning calorimetry (DSC) measurement indicated that the presence of CMCB accelerated the reduction of glass transition, and melting temperatures. Moreover the CMCB could improve the storage modulus of PLA composites at high temperature because its cold crystallization was developed. At room temperature, the tensile strength and elongation of PLA composite (but not modulus) were not significantly different with an increase of CMCB contents.


2020 ◽  
Vol 8 (3) ◽  
pp. 301-317
Author(s):  
Karima Ben Hamou ◽  
Amal Kadimi ◽  
Remo Merijs Meri ◽  
Sergei Gaidukov ◽  
Hamid Kaddami ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document