Limiting Behavior of Eigenvectors of Large Wigner Matrices

2011 ◽  
Vol 146 (3) ◽  
pp. 519-549 ◽  
Author(s):  
Z. D. Bai ◽  
G. M. Pan
2019 ◽  
Author(s):  
Chem Int

The kinetics of oxidation of methyl orange by vanadium(V) {V(V)} has been investigated in the pH range 2.3-3.79. In this pH range V(V) exists both in the form of decavanadates and VO2+. The kinetic results are distinctly different from the results obtained for the same reaction in highly acidic solution (pH < 1) where V(V) exists only in the form of VO2+. The reaction obeys first order kinetics with respect to methyl orange but the rate has very little dependence on total vanadium concentration. The reaction is accelerated by H+ ion but the dependence of rate on [H+] is less than that corresponding to first order dependence. The equilibrium between decavanadates and VO2+ explains the different kinetic pattern observed in this pH range. The reaction is markedly accelerated by Triton X-100 micelles. The rate-[surfactant] profile shows a limiting behavior indicative of a unimolecular pathway in the micellar pseudophase.


2021 ◽  
Vol 9 ◽  
Author(s):  
Zhigang Bao ◽  
László Erdős ◽  
Kevin Schnelli

Abstract We prove that the energy of any eigenvector of a sum of several independent large Wigner matrices is equally distributed among these matrices with very high precision. This shows a particularly strong microcanonical form of the equipartition principle for quantum systems whose components are modelled by Wigner matrices.


Author(s):  
Dexter Cahoy ◽  
Elvira Di Nardo ◽  
Federico Polito

AbstractWithin the framework of probability models for overdispersed count data, we propose the generalized fractional Poisson distribution (gfPd), which is a natural generalization of the fractional Poisson distribution (fPd), and the standard Poisson distribution. We derive some properties of gfPd and more specifically we study moments, limiting behavior and other features of fPd. The skewness suggests that fPd can be left-skewed, right-skewed or symmetric; this makes the model flexible and appealing in practice. We apply the model to real big count data and estimate the model parameters using maximum likelihood. Then, we turn to the very general class of weighted Poisson distributions (WPD’s) to allow both overdispersion and underdispersion. Similarly to Kemp’s generalized hypergeometric probability distribution, which is based on hypergeometric functions, we analyze a class of WPD’s related to a generalization of Mittag–Leffler functions. The proposed class of distributions includes the well-known COM-Poisson and the hyper-Poisson models. We characterize conditions on the parameters allowing for overdispersion and underdispersion, and analyze two special cases of interest which have not yet appeared in the literature.


1973 ◽  
Vol 1 (2) ◽  
pp. 297-311 ◽  
Author(s):  
P. K. Sen ◽  
B. B. Bhattacharyya ◽  
M. W. Suh
Keyword(s):  

2000 ◽  
Vol 34 (2) ◽  
pp. 353-376
Author(s):  
Ciprian Foias ◽  
Michael S. Jolly ◽  
Oscar P. Manley
Keyword(s):  

2011 ◽  
Vol 133 (8) ◽  
Author(s):  
Dong-Hyeog Yoon ◽  
Kyung-Soo Yang ◽  
Klaus Bremhorst

Characteristics of turbulent mass transfer around a rotating circular cylinder have been investigated by Direct Numerical Simulation. The concentration field was computed for three different cases of Schmidt number, Sc = 1, 10 and 100 at ReR* = 336. Our results confirm that the thickness of the Nernst diffusion layer decreases as Sc increases. Wall-limiting behavior within the diffusion layer was examined and compared with that of channel flow. Concentration fluctuation time scale was found to scale with r+2, while the time scale ratio nearly equals the Schmidt number throughout the diffusion layer. Scalar modeling closure constants based on gradient diffusion models were found to vary considerably within the diffusion layer. Results of an octant analysis show the significant role played by the ejection and sweep events just as is found for flat plate, channel, and pipe flow boundary layers. Turbulence budgets revealed a strong Sc dependence of turbulent scalar transport.


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