One-pot synthesis of 1-acetylpyrene over supported phosphotungstic heteropoly acid catalysts

2012 ◽  
Vol 108 (2) ◽  
pp. 531-544 ◽  
Author(s):  
Min-Qiang He ◽  
Ai-Xia Pan ◽  
Ji-Min Xie ◽  
De-Li Jiang ◽  
Xin-Hua Yuan ◽  
...  
2011 ◽  
Vol 8 (2) ◽  
pp. 689-696 ◽  
Author(s):  
Fatemeh F. Bamoharram ◽  
Ali Ahmadpour ◽  
Majid M. Heravi ◽  
Mohammad J. Sane Charkhi

A rapid and efficient one-pot method for the synthesis ofβ-acetamido ketones/esters has been developed in the presence of bulk tungstophosphoric acid and its supported forms on activated carbon as recyclable and eco-friendly catalysts under refluxing conditions. Supported tungstophosphoric acid catalysts containing the same amount of heteropoly acid yielded much higher conversion than bulk form.


2006 ◽  
Vol 243 (2) ◽  
pp. 258-263 ◽  
Author(s):  
Enio José Leão Lana ◽  
Kelly A. da Silva Rocha ◽  
Ivan V. Kozhevnikov ◽  
Elena V. Gusevskaya

RSC Advances ◽  
2020 ◽  
Vol 10 (48) ◽  
pp. 28856-28864 ◽  
Author(s):  
Nikolay V. Gromov ◽  
Tatiana B. Medvedeva ◽  
Yulia A. Rodikova ◽  
Dmitrii E. Babushkin ◽  
Valentina N. Panchenko ◽  
...  

Influence of composition of catalysts based on heteropoly acid cesium salts on formic acid production via starch hydrolysis–oxidation was investigated.


2010 ◽  
Vol 102 (1) ◽  
pp. 103-111 ◽  
Author(s):  
Min Chen ◽  
Yin-Yin Wu ◽  
Ying Luo ◽  
Min-Qiang He ◽  
Ji-Min Xie ◽  
...  

2012 ◽  
Vol 560-561 ◽  
pp. 294-299
Author(s):  
Xiao Qing Lu ◽  
Min Xing ◽  
Ai Xia Pan ◽  
Yin Yin Wu ◽  
Ji Min Xie ◽  
...  

A novel one-pot catalytic synthesis of 1-benzoylpyrene through acylation of pyrene with benzoyl chloride catalyzed by various Keggin type heteropoly acids (salts) was investigated. Pure 1-benzoylpyrene was obtained and the structure of 1-benzoylpyrene was identified by GC/MS, FT-IR and 1H NMR spectra. H3PW12O40 (PW) was found to be the most active catalyst in the acylation. The yield and the selectivity of 1-benzoylpyrene were up to 97.6 % and 100 %, respectively. The effects of experimental parameters on the catalytic acylation reaction and the recycling performance of PW catalyst were studied. PW catalyst shows well catalytic activity after running for 5 times. The facile product separation and the recycling performance of PW catalyst is expected to contribute to the development of clean and environmentally friendly strategy for the synthesis of 1-benzoylpyrene.


ChemSusChem ◽  
2018 ◽  
Vol 11 (17) ◽  
pp. 2870-2880 ◽  
Author(s):  
Andrea Garcia-Ortiz ◽  
Karen S. Arias ◽  
Maria J. Climent ◽  
Avelino Corma ◽  
Sara Iborra

2007 ◽  
Vol 48 (30) ◽  
pp. 5239-5242 ◽  
Author(s):  
Manas Chakrabarty ◽  
Ajanta Mukherji ◽  
Ratna Mukherjee ◽  
Shiho Arima ◽  
Yoshihiro Harigaya

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