Radical decomposition reactions: factors affecting transition-state energetics and geometries

2016 ◽  
Vol 65 (8) ◽  
pp. 1910-1929 ◽  
Author(s):  
E. T. Denisov ◽  
T. S. Pokidova
Keyword(s):  
Transition State ◽  
Factors Affecting ◽  
Decomposition Reactions ◽  
Radical Decomposition

scholarly journals Assessing the effective factors affecting the conformational preferences and the early and late transition states of the unimolecular retro-ene decomposition reactions of ethyl cyanate, ethyl thiocyanate and ethyl selenocyanate

RSC Advances ◽  
2017 ◽  
Vol 7 (37) ◽  
pp. 22757-22770 ◽  
Author(s):  
Hooshang Atabaki ◽  
Davood Nori-Shargh ◽  
Mohamad Momen-Heravi
Keyword(s):  
Transition States ◽  
Factors Affecting ◽  
Effective Factors ◽  
Decomposition Reactions ◽  
Barrier Heights ◽  
Conformational Preferences ◽  
Late Transition

The variations of Δ[(HCGAE(X3–C4weakening) – HCGAE(X3–C4strengthening)] parameters correlate well with the variations of the retro-ene decomposition reactions barrier heights going from compound1to compound3.

The Role of the Solvent in Radical Decomposition Reactions: p-Nitrophenylazotris-(p-anisyl)-methane

1954 ◽  
Vol 76 (16) ◽  
pp. 4169-4171 ◽  
Author(s):  
Mendel D. Cohen ◽  
John E. Leffler ◽  
Libero M. Barbato
Keyword(s):  
Decomposition Reactions ◽  
Radical Decomposition

THE EFFECT OF COMPLEXING IN RADICAL DECOMPOSITION REACTIONS

1954 ◽  
Vol 19 (7) ◽  
pp. 1089-1096 ◽  
Author(s):  
JOHN E. LEFFLER ◽  
R. A. HUBBARD
Keyword(s):  
Decomposition Reactions ◽  
Radical Decomposition

Theoretical study of alkoxyl radical decomposition reactions: structure–activity relationships

2000 ◽  
Vol 2 (17) ◽  
pp. 3765-3772 ◽  
Author(s):  
Raphaël Me´reau ◽  
Marie-The´rèse Rayez ◽  
Françoise Caralp ◽  
Jean-Claude Rayez
Keyword(s):  
Theoretical Study ◽  
Alkoxyl Radical ◽  
Structure Activity Relationships ◽  
Decomposition Reactions ◽  
Structure Activity ◽  
Radical Decomposition

scholarly journals Methods of extinguishing plastics used in the construction of means of public transport - factors affecting fire extinguishing efficiency

2019 ◽  
Vol 20 (1-2) ◽  
pp. 113-118
Author(s):  
Dariusz Pietrzela ◽  
Katarzyna Skorupka ◽  
Daria Kubis
Keyword(s):  
Public Transport ◽  
Water Mist ◽  
Test Methods ◽  
Factors Affecting ◽  
Decomposition Reactions ◽  
Fire Extinguishing ◽  
Performance Requirements ◽  
Current Trends ◽  
Plastic Materials ◽  
Transport Factors

The article analyzes the methods of extinguishing plastic materials, mainly polymer ones, occurring in the construction of means of public transport, ie. buses, trams, trains, metro etc. The characteristics of flammability and decomposition reactions were discussed and this was confronted with the characteristics of wood decomposition as an interchangeable material in extinguishing tests according to the Polish standard PN-EN 3-7 "Portable fire extinguishers - Part 7: Characteristics, performance requirements and test methods" due to the com-mon occurrence of these firefighting devices in both buses and other public transport. In addition, other methods of extinguishing means of public transport resulting from current trends, i.e. aerosol systems and water mist, have been indicated. The extinguishing methods were confronted, indicating their advantages, disadvantages and application possibilities in means of public transport, including buses..

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