THE EFFECT OF COMPLEXING IN RADICAL DECOMPOSITION REACTIONS

1954 ◽  
Vol 19 (7) ◽  
pp. 1089-1096 ◽  
Author(s):  
JOHN E. LEFFLER ◽  
R. A. HUBBARD
Keyword(s):  
Decomposition Reactions ◽  
Radical Decomposition

The Role of the Solvent in Radical Decomposition Reactions: p-Nitrophenylazotris-(p-anisyl)-methane

1954 ◽  
Vol 76 (16) ◽  
pp. 4169-4171 ◽  
Author(s):  
Mendel D. Cohen ◽  
John E. Leffler ◽  
Libero M. Barbato
Keyword(s):  
Decomposition Reactions ◽  
Radical Decomposition

Theoretical studies on p-pyridyl radical decomposition reactions

2004 ◽  
Vol 678 (1-3) ◽  
pp. 17-21 ◽  
Author(s):  
Xue Li Cheng ◽  
Yan Yun Zhao ◽  
Zheng Yu Zhou
Keyword(s):  
Theoretical Studies ◽  
Decomposition Reactions ◽  
Radical Decomposition

Theoretical study of alkoxyl radical decomposition reactions: structure–activity relationships

2000 ◽  
Vol 2 (17) ◽  
pp. 3765-3772 ◽  
Author(s):  
Raphaël Me´reau ◽  
Marie-The´rèse Rayez ◽  
Françoise Caralp ◽  
Jean-Claude Rayez
Keyword(s):  
Theoretical Study ◽  
Alkoxyl Radical ◽  
Structure Activity Relationships ◽  
Decomposition Reactions ◽  
Structure Activity ◽  
Radical Decomposition

Arrhenius parameters for the alkoxy radical decomposition reactions

1981 ◽  
Vol 13 (9) ◽  
pp. 833-844 ◽  
Author(s):  
Kwang Yul Choo ◽  
Sidney W. Benson
Keyword(s):  
Alkoxy Radical ◽  
Arrhenius Parameters ◽  
Decomposition Reactions ◽  
Radical Decomposition

The Role of the Solvent in Radical Decomposition Reactions: Phenylazotriphenylmethane

1954 ◽  
Vol 76 (5) ◽  
pp. 1425-1427 ◽  
Author(s):  
Marilyn G. Alder ◽  
John E. Leffler
Keyword(s):  
Decomposition Reactions ◽  
Radical Decomposition

Radical decomposition reactions: factors affecting transition-state energetics and geometries

2016 ◽  
Vol 65 (8) ◽  
pp. 1910-1929 ◽  
Author(s):  
E. T. Denisov ◽  
T. S. Pokidova
Keyword(s):  
Transition State ◽  
Factors Affecting ◽  
Decomposition Reactions ◽  
Radical Decomposition

Non-Isothermal Decomposition Kinetic of Polypropylene/Hydrotalcite Composite

2019 ◽  
Vol 19 (11) ◽  
pp. 7493-7501 ◽  
Author(s):  
Sheng Xu ◽  
Min Zhang ◽  
Siyu Li ◽  
Moyu Yi ◽  
Shigen Shen ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Thermal Decomposition ◽  
Nitrogen Atmosphere ◽  
Heating Rates ◽  
Decomposition Reactions ◽  
Kinetic And Thermodynamic Parameters ◽  
Málek Method ◽  
Boundary Reaction ◽  
Phase Boundary Reaction ◽  
Thermal Stability Of

P3O5-10 pillared Mg/Al hydrotalcite (HTs) as a functional fire-retarding filler was successfully prepared by impregnation-reconstruction, where the HTs was used to prepare polypropylene (PP) and HTs composite (PP/HTs). Thermal decomposition was crucial for correctly identifying the thermal behavior for the PP/HTs, and studied using thermogravimetry (TG) at different heating rates. Based on single TG curves and Málek method, as well as 41 mechanism functions, the thermal decompositions of the PP/HTs composite and PP in nitrogen atmosphere were studied under non-isothermal conditions. The mechanism functions of the thermal decomposition reactions for the PP/HTs composite and PP were separately “chemical reaction F3” and “phase boundary reaction R2,” which were also in good agreement with corresponding experimental data. It was found that the addition of the HTs increased the apparent activation energy Ea of the PP/HTs comparing to the PP, which improved the thermal stability of the polypropylene. A difference in the set of kinetic and thermodynamic parameters was also observed between the PP/HTs and PP, particularly with respect to lower ΔS≠ value assigned to higher thermal stability of the PP/HTs composite.

Thermal decomposition reactions of carboxybenzenediazonium salts. I. 1,4-Dehydroaromatic compounds from o-carboxybenzenediazonium salts

1970 ◽  
Vol 35 (10) ◽  
pp. 3328-3332 ◽  
Author(s):  
Rita. Hoyos de Rossi ◽  
Hector E. Bertorello ◽  
Roberto A. Rossi
Keyword(s):  
Thermal Decomposition ◽  
Decomposition Reactions
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