Palladium supported on triphenylphosphine-functionalized porous organic polymer: an efficient heterogeneous catalyst for aminocarbonylation

2015 ◽  
Vol 41 (1) ◽  
pp. 1-7 ◽  
Author(s):  
Yizhu Lei ◽  
Xuefeng Zhang ◽  
Yanlong Gu ◽  
Jianglin Hu ◽  
Guangxing Li ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Efficient Heterogeneous Catalyst

scholarly journals Conversion of CO2 into Chloropropene Carbonate Catalyzed by Iron (II) Phthalocyanine Hypercrosslinked Porous Organic Polymer

Molecules ◽  
2020 ◽  
Vol 25 (20) ◽  
pp. 4598
Author(s):  
Eva M. Maya ◽  
Antonio Valverde-González ◽  
Marta Iglesias
Keyword(s):  
Heterogeneous Catalyst ◽  
Direct Synthesis ◽  
Cyclic Carbonate ◽  
Organic Polymer ◽  
Iron Loading ◽  
Reaction Conditions ◽  
Porous Organic Polymer ◽  
Commercial Iron ◽  
Excellent Stability ◽  
Efficient Heterogeneous Catalyst

Commercial iron (II) phthalocyanine (FePc) was knitted with biphenyl using a Friedel–Crafts reaction to yield a micro-meso porous organic polymer (FePc-POP) with a specific surface area of 427 m2/g and 5.42% of iron loading. This strategy allowed for the direct synthesis of a heterogeneous catalyst from an iron containing monomer. The catalytic system, formed by the knitted polymer containing FePc and DMAP (4-dimethylamino pyridine) as base, results in an efficient heterogeneous catalyst in the cycloaddition of CO2 to epichlorohydrin to selectively obtain the corresponding cyclic carbonate. Thus, a TON (mmol substrate converted/mmol catalysts used) value of 2700 was reached in 3 h under mild reaction conditions (solvent free, 90 °C, 3 bar of CO2). The catalyst does not exhibit leaching during the reactions, which was attributed to the excellent stability of the metal in the macrocycle.

scholarly journals Nickel-metalated porous organic polymer for Suzuki–Miyaura cross-coupling reaction

RSC Advances ◽  
2019 ◽  
Vol 9 (35) ◽  
pp. 20266-20272 ◽  
Author(s):  
Ying Dong ◽  
Jing-Jing Jv ◽  
Yue Li ◽  
Wen-Han Li ◽  
Yun-Qi Chen ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Highly Active ◽  
Cross Coupling Reaction

A porous organic polymer with Ni(ii) α-diimine moiety, which can be a highly active reusable heterogeneous catalyst to promote the Suzuki–Miyaura coupling reaction, was reported.

Porous Organic Polymer Supported Rhodium as a Reusable Heterogeneous Catalyst for Hydroformylation of Olefins

2019 ◽  
Vol 21 (7) ◽  
pp. 2147-2150 ◽  
Author(s):  
Xiaofei Jia ◽  
Zuyu Liang ◽  
Jianbin Chen ◽  
Jinhe Lv ◽  
Kai Zhang ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Polymer Supported

scholarly journals Highly Efficient Heterogeneous Pd@POPs Catalyst for the N-Formylation of Amine and CO2

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 220
Author(s):  
Guoqing Wang ◽  
Miao Jiang ◽  
Guangjun Ji ◽  
Zhao Sun ◽  
Lei Ma ◽  
...  
Keyword(s):  
Active Sites ◽  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Highly Efficient ◽  
Surface Areas ◽  
Uniform Dispersion ◽  
Excellent Activity ◽  
Long Time ◽  
Hierarchical Pore ◽  
Efficient Heterogeneous Catalyst

Utilization of CO2 for the production of fine chemicals has become a research hotspot for a long time. In order to make use of CO2, we developed a highly efficient heterogeneous catalyst (denoted as Pd@POPs) for the N-formylation reaction of amine and CO2 under mild conditions. The Pd catalyst was based on a porous organic polymer derived from the solvothermal polymerization of vinyl-functionalized PPh3. A series of characterizations and comparative experiments demonstrated that the Pd@POPs catalyst has high BET (Brunauer-Emmett-Teller) surface areas, hierarchical pore structure, and uniform dispersion of Pd active sites resulting from the formation of strong coordination bonds between Pd species and P atoms in the porous organic polymer (POP) support. In addition to the excellent activity, the Pd@POPs catalyst shows good stability for the N-formylation reaction of amine and CO2.

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