The rate of substitution from η6-arene ruthenium(II) complexes

2020 ◽  
Vol 45 (5) ◽  
pp. 305-315 ◽  
Author(s):  
Meshack K. Sitati ◽  
Deogratius Jaganyi ◽  
Allen Mambanda
Keyword(s):  
2021 ◽  
Vol 11 (7) ◽  
pp. 3050
Author(s):  
Eva M. García del Toro ◽  
Daniel Alcala-Gonzalez ◽  
María Isabel Más-López ◽  
Sara García-Salgado ◽  
Santiago Pindado

Silicon is the main element in the composition of glass and it has been seen that it can be used as a partial replacement for cement in the manufacture of concrete. Different dosages of glass powder and cement were applied to manufacture the concrete mixes. Initially, the characteristics of fresh concrete were studied, such as consistency, air content, apparent density and workability. Secondly, compressive strength tests were performed on the different concrete mixtures produced. The consistency tests allowed us to classify these concretes within the group of fluids. The air content of these concretes increased with the rate of substitution of cement by glass powder, resulting in lighter concretes. Density tests showed that this parameter decreased as the rate of substitution of cement increased. A coefficient k has been calculated for the substitution of glass powder by cement in the binder, using the Bolomey formula. Also, a mathematical model has been proposed to further analyze the experimental data. Major contributions of this work were to study the possible application of this concrete in different dispersions as a surface protection layer against the action of corrosion, in wind turbine foundations as well as the stabilization of the wind farm roads.


2021 ◽  
Author(s):  
Chee Hon Chan

Abstract Background Research has highlighted that satisfaction in health and social support are key areas of life affecting individual’s wellbeing. Many social and public health initiatives use these two intervention mechanisms to improve individual’s wellbeing. For the purpose of cost-benefit assessment, there has been growing interest in expressing these intervention effects in economic terms. However, only a handful of studies have ever estimated these effects in economic terms, and none of which examined in a Chinese context. The aim of this study is to extend this line of valuation work to estimate the implicit willingness-to-pays on the effects of improving individuals’ self-rated health status (SRH) and social support (SS) on their life satisfaction in the Chinese population. Methods Using individual’s life satisfaction data from a two-wave representative panel survey in Hong Kong (n = 1,109), this study first conducted a cross-lagged analysis with structural equation modelling technique to examine the causal effects of SRH and SS on life satisfaction, while simultaneously adjusting their reverse causal influences. The use of this cross-lagged approach was the effort to minimising the endogeneity problem. Then, substituting the respective estimates to the formulae of compensating surplus, the marginal rate of substitution of SRH and SS with respect to individual’s equivalised monthly household were estimated and were then expressed as the willingness-to-pays on the effect of improving individuals’ SRH and SS on their life satisfaction. Results The cross-lagged analysis ascertained the casual effects of SRH (β = 0.078, 95%CI: 0.020, 0.151) and SS on individuals’ satisfaction with life. The sample’s marginal rate of substitution of SRH and SS were found to be 1.28 (95%CI: 0.43, 2.15) and 1.36 (95%CI: 0.23, 2.49) respectively. Translating into the concept of compensating surplus, the implicit monetary values of improving the sample’s SRH from “poor health” to “excellent health” and their SS from “little support” to “a lot of support” are equivalent to an increase in their equivalised monthly household income by HK$56,000 and HK$39,400 respectively. Conclusions This study has implications for the cost-benefit assessment in wellbeing initiatives for the Chinese population.


2015 ◽  
Vol 2015 (1) ◽  
pp. 12090
Author(s):  
Andrea Signori ◽  
Josip Kotlar ◽  
Alfredo De Massis ◽  
Silvio Vismara

2011 ◽  
Vol 279 (1735) ◽  
pp. 2003-2011 ◽  
Author(s):  
Martin Ryberg ◽  
P. Brandon Matheny

The ectomycorrhizal (ECM) symbiosis is the most widespread biotrophic nutritional mode in mushroom-forming fungi. ECM fungi include, though are not limited to, about 5000 described species of Agaricales from numerous, independently evolved lineages. Two central hypotheses suggest different explanations for the origin of ECM fungal diversity: (i) dual origins, initially with the Pinaceae in the Jurassic and later with angiosperms during the Late Cretaceous, and (ii) a simultaneous and convergent radiation of ECM lineages in response to cooling climate during the Palaeogene and advancing temperate ECM plant communities. Neither of these hypotheses is supported here. While we demonstrate support for asynchronous origins of ECM Agaricales, the timing of such events appears to have occurred more recently than suggested by the first hypothesis, first during the Cretaceous and later during the Palaeogene. We are also unable to reject models of rate constancy, which suggests that the diversity of ECM Agaricales is not a consequence of convergent rapid radiations following evolutionary transitions from saprotrophic to ECM habits. ECM lineages of Agaricales differ not only in age, but also in rates of diversification and rate of substitution at nuclear ribosomal RNA loci. These results question the biological uniformity of the ECM guild.


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