Salt Concentration Measurement Using Re-usable Electric Conductivity–based Sensors

2021 ◽  
Vol 232 (1) ◽  
Author(s):  
Rohan Benjankar ◽  
Ravin Kafle
SPE Journal ◽  
2011 ◽  
Vol 16 (03) ◽  
pp. 548-558 ◽  
Author(s):  
I.I.. I. Bogdanov ◽  
J.A.. A. Torres ◽  
H.A.. A. Akhlaghi ◽  
A.M.. M. Kamp

Summary Steam injection is often not a good alternative for oil recovery from shallow bitumen reservoirs. For instance, the thin caprock creates the danger of steam breakthrough. For deeper reservoirs, the heat losses from injection wells may be prohibitive. A technology that may be better suited is oil recovery aided by low-frequency electrical heating of the reservoir. This technology, well known for environmental remedial applications, has been field tried recently, yielding promising results. The process uses electric conductivity of connate water to propagate an alternating current between electrodes, inducing the Joule heating of the reservoir. An associated problem is the appearance of hot spots around the electrodes that may be relieved by water circulation. However, the water circulation may have a significant effect on the heating process because the electric conductivity of the circulated water depends on its salt content. To find out the influence of salt concentration on process efficiency, we have studied the process of salt-water recirculation around an electrode using numerical simulation. The physical properties and operational data for Athabasca bitumen have been collected from the literature. The model built with Computer Modelling Group's STARS simulator and tested first with available analytical solutions has been validated, and the proper choice of the underlying grid and numerical tuning parameters has been verified. The process was also simulated at field scale for a common pattern of electrodes and production wells. The salt penetrated into the reservoir, far beyond the major water-circulation zone around the electrodes. This process increases the electric conductivity in a large region between electrodes, which improves the heating of the reservoir. The single-electrode simulation studies using different tools yielded similar results for a simple problem. More-complex (and more-realistic) field-scale simulations show that adding salt enhances the oil production. In practice, an upper concentration limit may be given by corrosion problems at the electrodes. The reservoir simulation of bitumen recovery assisted by low-frequency heating is a challenging multiphysics problem. The understanding of the influence of salt concentration on the circulated water provided by this work is an important key in process-design considerations.


1989 ◽  
Vol 47 (3) ◽  
pp. 151-156
Author(s):  
Sachiko Ohno ◽  
Hisae Aoki ◽  
Sumi Asakusa

1931 ◽  
Vol 8 (1) ◽  
pp. 82-94
Author(s):  
C. F. A. PANTIN

1. The rate of loss of salts by the estuarine worm, Gunda ulvae, on transference from sea water to various dilute solutions has been studied by measurement of the electric conductivity of the solutions. 2. Salts are lost by the worms from the moment of immersion in dilute solutions. Conditions affecting the rate of loss of salts are discussed. 3. The relation between the amount of salts lost and the total electrolyte content of the worm was determined. It is shown that the worms only lose 25 per cent. of their salts during the time that they imbibe a volume of water from the dilute solution equal to their initial volume. 4. The limiting internal salt concentration of worms surviving in waters containing calcium is about 6-10 per cent. of the normal concentration in sea water. No such limiting value can be found for distilled water, since salts are lost continuously till cytolysis occurs. The significance of the limiting concentration is discussed. 5. The effect of osmotic pressure, pH, dilute solutions of NaCl, NaHCO3, glycerol, CaCl2 and CaCO3 are studied. The presence of calcium reduces the rate of loss of salts. Other factors do not seem to influence this rate. 6. The relation of calcium to the maintenance of normal permeability to water and salts in the worm, and the significance of this to the problem of migration into fresh water are discussed.


2014 ◽  
Vol 53 (6S) ◽  
pp. 06JE04 ◽  
Author(s):  
Cheng-Chih Hsu ◽  
Chia Yu Yang ◽  
Chiu-Jung Lai ◽  
Ching-Lian Dai

1983 ◽  
Vol 80 ◽  
pp. 315-323 ◽  
Author(s):  
Marc Lindheimer ◽  
Jean-Claude Montet ◽  
Roselyne Bontemps ◽  
Jacques Rouviere ◽  
Bernard Brun

2018 ◽  
Author(s):  
Nicola Molinari ◽  
Jonathan P. Mailoa ◽  
Boris Kozinsky

<div> <div> <div> <p>The model and analysis methods developed in this work are generally applicable to any polymer electrolyte/cation-anion combination, but we focus on the currently most prominent polymer electrolyte material system: poly(ethylene) oxide/Li- bis(trifluoromethane) sulfonamide (PEO + LiTFSI). The obtained results are surprising and challenge the conventional understanding of ionic transport in polymer electrolytes: the investigation of a technologically relevant salt concentration range (1 - 4 M) revealed the central role of the anion in coordinating and hindering Li ion movement. Our results provide insights into correlated ion dynamics, at the same time enabling rational design of better PEO-based electrolytes. In particular, we report the following novel observations. 1. Strong binding of the Li cation with the polymer competes with significant correlation of the cation with the salt anion. 2. The appearance of cation-anion clusters, especially at high concentration. 3. The asymmetry in the composition (and therefore charge) of such clusters; specifically, we find the tendency for clusters to have a higher number of anions than cations.</p> </div> </div> </div>


2018 ◽  
Author(s):  
Nicola Molinari ◽  
Jonathan P. Mailoa ◽  
Boris Kozinsky

<div> <div> <div> <p>The model and analysis methods developed in this work are generally applicable to any polymer electrolyte/cation-anion combination, but we focus on the currently most prominent polymer electrolyte material system: poly(ethylene) oxide/Li- bis(trifluoromethane) sulfonamide (PEO + LiTFSI). The obtained results are surprising and challenge the conventional understanding of ionic transport in polymer electrolytes: the investigation of a technologically relevant salt concentration range (1 - 4 M) revealed the central role of the anion in coordinating and hindering Li ion movement. Our results provide insights into correlated ion dynamics, at the same time enabling rational design of better PEO-based electrolytes. In particular, we report the following novel observations. 1. Strong binding of the Li cation with the polymer competes with significant correlation of the cation with the salt anion. 2. The appearance of cation-anion clusters, especially at high concentration. 3. The asymmetry in the composition (and therefore charge) of such clusters; specifically, we find the tendency for clusters to have a higher number of anions than cations.</p> </div> </div> </div>


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