scholarly journals Hydrothermal deposition as a novel method for the preparation of Co–Mn mixed oxide catalysts supported on stainless steel meshes: application to VOC oxidation

Author(s):  
Pavel Topka ◽  
Květuše Jirátová ◽  
Michaela Dvořáková ◽  
Jana Balabánová ◽  
Martin Koštejn ◽  
...  
2021 ◽  
Author(s):  
Pavel Topka ◽  
Květuše Jirátová ◽  
Michaela Dvořáková ◽  
Jana Balabánová ◽  
Martin Koštejn ◽  
...  

Abstract The aim of this work was to develop a novel method for the preparation of structured Co-Mn mixed oxide catalysts: deposition on stainless steel meshes by hydrothermal synthesis. The use of meshes enabled the deposition of a thin layer of the active phase, which significantly suppressed the influence of internal diffusion. Consequently, the prepared catalysts exhibited from 48 to 114 times higher catalytic activity in ethanol oxidation than the commercial pelleted Co-Mn-Al catalyst. Moreover, we have shown that their catalytic activity correlated with the amount of surface oxygen vacancies determined by XPS. Finally, the outstanding activity of the catalyst with Co:Mn ratio of 0.5 was ascribed to the mutual effect of high number of oxygen vacancies and exceptional redox properties.


ACS Catalysis ◽  
2021 ◽  
pp. 10294-10307
Author(s):  
Satoshi Ishikawa ◽  
Yudai Yamada ◽  
Naoki Kashio ◽  
Nagisa Noda ◽  
Kosuke Shimoda ◽  
...  

2014 ◽  
Vol 469 ◽  
pp. 165-172 ◽  
Author(s):  
K. Jagadeeswaraiah ◽  
Ch. Ramesh Kumar ◽  
P.S. Sai Prasad ◽  
S. Loridant ◽  
N. Lingaiah

2016 ◽  
Vol 6 (1) ◽  
pp. 125-133 ◽  
Author(s):  
Neetika Madaan ◽  
N. Raveendran Shiju ◽  
Gadi Rothenberg

Mix & match: we show that combining simple heuristic models with experimental validation is an effective method for optimising supported mixed oxide catalysts.


2011 ◽  
Vol 28 (4) ◽  
pp. 1139-1143 ◽  
Author(s):  
Moon Hyeon Kim ◽  
Kyung Ho Cho ◽  
Chae-Ho Shin ◽  
Seong-Eun Kang ◽  
Sung-Won Ham

2022 ◽  
Author(s):  
Zhitao Han ◽  
Huan Du ◽  
Duo Xu ◽  
Yu Gao ◽  
Shaolong Yang ◽  
...  

FeMn/SnxTiO2 catalysts were synthesized by introducing Sn as an additive to modify TiO2 supports, and the Sn doping could improve the SO2 tolerance and low-temperature SCR activity significantly.


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