Adsorption and inhibition effect of 2,4-diamino-6-hydroxypyrimidine for mild steel corrosion in HCl medium: experimental and theoretical investigation

Ionics ◽  
2018 ◽  
Vol 25 (2) ◽  
pp. 859-870 ◽  
Author(s):  
Reşit Yıldız
2014 ◽  
Vol 85 ◽  
pp. 287-295 ◽  
Author(s):  
Başak Doğru Mert ◽  
Ayşe Ongun Yüce ◽  
Gülfeza Kardaş ◽  
Birgül Yazıcı

Author(s):  
Lebe A. Nnanna ◽  
Wisdom O. John ◽  
Tochukwu E. Esihe ◽  
Kelechi C. Denkoro ◽  
Victor I. Okparaku ◽  
...  

Inhibition effect of Costusafer on mild steel in 0.5 M HCl was studied using gravimetric method at room temperature. It was found out that Costusafer inhibited the corrosion of mild steel in the acidic environment and that the efficiency of inhibition increased as the concentration of the inhibitor in the environment increased. The data was used to test different isotherms and it suited the Langmuir isotherm. A value of -15.995 kJmol-1 was gotten for the ∆Goads. This value showed that the extracts of Costusafer inhibited the corrosion process through physiosorption mechanism. The high value of inhibition efficiency of the extract as the concentration increased in rationalized in terms of the increase in herteroatoms, saponnins and tannins which are present in the extract.


2018 ◽  
Vol 50 (8) ◽  
pp. 779-789 ◽  
Author(s):  
B.M. Prasanna ◽  
B.M. Praveen ◽  
Narayan Hebbar ◽  
M.K. Pavithra ◽  
T.S. Manjunatha ◽  
...  

2012 ◽  
Vol 9 (3) ◽  
pp. 1632-1644 ◽  
Author(s):  
R. Rajalakshmi ◽  
A. S. Safina

Corrosion control methods, especially the use of inhibitors, have gained monumental importance in the present scenario of expunging corrosion and the quest for eco-friendly reasons continues. To arrive at an inexpensive non-toxic, eco-friendly inhibitor formulations the present study on the use of Staminate Flower extract of Cocos Nucifera has been carried out by the classical weight loss measurements and electrochemical polarization measurements. The acid extract could bring out a maximum of 97.3% inhibition of mild steel corrosion in 1M HCl. Thermodynamic parameters of the corrosion process were calculated from temperature study. The adsorptive behaviour of Staminate Flower extract in acid solution may be approximated both by Langmuir and Temkin type isotherms. The results obtained by Tafel, Linear polarization resistance, and impedance spectroscopy have been correlated with the classical weight loss measurements. Values of Tafel constant ba and bc confirmed that the Staminate Flower extract acts like mixed type inhibitor. Examination of the surface of the metal in the presence of the inhibitor confirmed the deposition of inhibitor on the metal surface. The Staminate Flower extract in HCl medium efficiently inhibits the corrosion and proved to be zero cost inhibitor, eco-friendly, non-toxic, and highly economical.


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