Mixed-Alkali Effect in Li2O–Na2O–K2O–B2O3 Glasses: Infrared and Optical Absorption Studies

2013 ◽  
Vol 42 (8) ◽  
pp. 2516-2524 ◽  
Author(s):  
M.A. Samee ◽  
A. Edukondalu ◽  
Shaik Kareem Ahmmad ◽  
Sair Md. Taqiullah ◽  
Syed Rahman
2009 ◽  
Vol 404 (12-13) ◽  
pp. 1785-1789 ◽  
Author(s):  
N. Srinivasa Rao ◽  
Shashidhar Bale ◽  
M. Purnima ◽  
Ch. Srinivasu ◽  
M.A. Samee ◽  
...  

2013 ◽  
Vol 22 ◽  
pp. 278-283
Author(s):  
A. EDUKONDALU ◽  
M. A. SAMEE ◽  
SHAIKH KAREEM AHMMAD ◽  
SAIR MD. TAQIULLAH ◽  
SYED RAHMAN ◽  
...  

Mixed alkali tungsten borate glasses xLi2O–(30–x) K2O–10WO3–60B2O3 (0 < x < 30) were prepared from the melts. These glasses were characterized using X-ray diffraction, differential scanning calorimetry and density measurements. Optical absorption studies were carried out as a function of alkali content to look for mixed alkali effect (MAE) on the spectral properties of these glasses. From the study of ultraviolet absorption edge, the optical band gap energies and Urbach energies were evaluated. The average electronic polarizability of the oxide ion, optical basicity and the interaction parameters were also evaluated for all the glasses. Many of these parameters vary non-linearly exhibiting a minima or maxima with increasing alkali concentration, indicating the mixed alkali effect. An attempt is made to interpret MAE in this glass system in terms of its glass structure.


2006 ◽  
Vol 41 (9) ◽  
pp. 1646-1656 ◽  
Author(s):  
R.P. Sreekanth Chakradhar ◽  
B. Yasoda ◽  
J. Lakshmana Rao ◽  
N.O. Gopal

1983 ◽  
Vol 2 (11) ◽  
pp. 697-700 ◽  
Author(s):  
Amit Sarkar ◽  
Ashok Dasgupta ◽  
Bharati Basu ◽  
A. Paul

2018 ◽  
Author(s):  
S. M. Taqiullah ◽  
Shaik Kareem Ahmmad ◽  
M. A. Samee ◽  
Syed Rahman

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