scholarly journals Anthracene modified graphene for C60/C70 fullerenes capture and construction of energy storage materials

2021 ◽  
Author(s):  
Agata Fedorczyk ◽  
Agnieszka Krogul-Sobczak ◽  
Piotr Piotrowski
Keyword(s):  
Energy Storage ◽  
Photoelectron Spectroscopy ◽  
Alder Reaction ◽  
Diels Alder ◽  
Energy Storage Materials ◽  
Diels Alder Reaction ◽  
Novel Approach ◽  
Capacitive Properties ◽  
Energy Storage Properties ◽  
Modified Graphene

AbstractGraphene functionalized with dianthracene malonate was synthesized and used subsequently for construction of covalently bound graphene-fullerene hybrid nanomaterials. For this purpose, novel approach of Diels–Alder reaction of C60/C70 fullerene cores with anthracene moieties previously introduced onto graphene surface was successfully employed. Structure and composition of obtained graphene and its derivatives were characterized using scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and FT-IR spectroscopy. Obtained results revealed that both C60 and C70 fullerenes were found to be capable of formation desired Diels–Alder adducts, yielding products of different morphology. Capacitive properties of the synthesized energy storage nanomaterials were determined by means of cyclic voltammetry (CV) and galvanostatic charge/discharge (GCD) measurements, revealing that functionalization of graphene with C60 moieties enhances its energy storage properties.

Novel approach to 3,3-dimethyl-4-morpholino-3,4-dihydrocoumarins via hetero-Diels–Alder reaction

Tetrahedron ◽  
2014 ◽  
Vol 70 (35) ◽  
pp. 5608-5618 ◽  
Author(s):  
Divya Mathur ◽  
Ashok K. Prasad ◽  
T. Stanley Cameron ◽  
Amitabh Jha
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Novel Approach

Thermally reliable, recyclable and malleable solid–solid phase-change materials through the classical Diels–Alder reaction for sustainable thermal energy storage

2019 ◽  
Vol 7 (38) ◽  
pp. 21802-21811 ◽  
Author(s):  
Bo Wu ◽  
Yi Wang ◽  
Zhimeng Liu ◽  
Yuan Liu ◽  
Xiaowei Fu ◽  
...  
Keyword(s):  
Renewable Energy ◽  
Energy Storage ◽  
Phase Change Materials ◽  
Solid Phase ◽  
Alder Reaction ◽  
Diels Alder ◽  
Energy Capture ◽  
Diels Alder Reaction ◽  
Renewable Energy Storage ◽  
Capture Capacity

DC-PCMs are facilely fabricated for renewable energy storage, and can be fully recycled and reshaped without sacrificing the energy-capture capacity.

scholarly journals Improvement of Mechanical and Self-Healing Properties for Polymethacrylate Derivatives Containing Maleimide Modified Graphene Oxide

Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 603 ◽  
Author(s):  
Won-Ji Lee ◽  
Sang-Ho Cha
Keyword(s):  
Mechanical Properties ◽  
Graphene Oxide ◽  
Alder Reaction ◽  
Diels Alder ◽  
The Self ◽  
Self Healing ◽  
Diels Alder Reaction ◽  
Healing Efficiency ◽  
Modified Graphene Oxide ◽  
Modified Graphene

In this paper, a self-healable nanocomposite based on the Diels-Alder reaction is developed. A graphene-based nanofiller is introduced to improve the self-healing efficiency, as well as the mechanical properties of the nanocomposite. Graphene oxide (GO) is modified with maleimide functional groups, and the maleimide-modified GO (mGO) enhanced the compatibility of the polymer matrix and nanofiller. The tensile strength of the nanocomposite containing 0.030 wt% mGO is improved by 172%, compared to that of a polymer film incorporating both furan-functionalized polymer and bismaleimide without any nanofiller. Moreover, maleimide groups of the surface on mGO participate in the Diels-Alder reaction, which improves the self-healing efficiency. The mechanical and self-healing properties are significantly improved by using a small amount of mGO.

scholarly journals Inherently chiral heterocyclic resorcinarenes using a Diels–Alder reaction

RSC Advances ◽  
2016 ◽  
Vol 6 (16) ◽  
pp. 13027-13031 ◽  
Author(s):  
W. Iwanek ◽  
K. Stefańska ◽  
A. Szumna ◽  
M. Wierzbicki
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diastereoselective Synthesis ◽  
Diels Alder Reaction ◽  
Novel Approach ◽  
Inherently Chiral

This paper presents a novel approach to highly diastereoselective synthesis of resorcinarenes having enlarged cavities.

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