Deterioration of hydrogen-bonded superprotonic conductors belonging to CsHSO4–CsH2PO4–H2O salt system: a single-crystal neutron diffraction investigation

2021 ◽  
Vol 44 (2) ◽  
Author(s):  
R R Choudhury ◽  
R Chitra ◽  
I P Makarova ◽  
E V Selezneva ◽  
V A Komornikov
Keyword(s):  
Neutron Diffraction ◽  
Single Crystal ◽  
Salt System ◽  
System A ◽  
Hydrogen Bonded

Et3NH+Co(CO)4-: hydrogen-bonded adduct or simple ion pair? Single-crystal neutron diffraction study at 15 K

1992 ◽  
Vol 11 (7) ◽  
pp. 2339-2341 ◽  
Author(s):  
Lee Brammer ◽  
Melinda C. McCann ◽  
R. Morris Bullock ◽  
Richard K. McMullan ◽  
Paul Sherwood
Keyword(s):  
Neutron Diffraction ◽  
Single Crystal ◽  
Diffraction Study ◽  
Neutron Diffraction Study ◽  
Ion Pair ◽  
Hydrogen Bonded

scholarly journals Operando single crystal neutron diffraction reveals insight into the field response mechanisms in the hydrogen-bonded KH2PO4 ferroelectric

APL Materials ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 021111
Author(s):  
C. M. Fancher ◽  
C. M. Hoffmann ◽  
X. P. Wang ◽  
L. L. Daemen ◽  
A. J. Schultz
Keyword(s):  
Neutron Diffraction ◽  
Single Crystal ◽  
Field Response ◽  
Insight Into ◽  
Hydrogen Bonded

SINGLE CRYSTAL NEUTRON DIFFRACTION STUDIES OF HCP RARE EARTH THORIUM ALLOYS

1971 ◽  
Vol 32 (C1) ◽  
pp. C1-1128-C1-1129
Author(s):  
H. R. CHILD ◽  
W. C. KOEHLER
Keyword(s):  
Rare Earth ◽  
Neutron Diffraction ◽  
Single Crystal

NEUTRON DIFFRACTION AND MAGNETIZATION STUDY OF THE MAGNETIC PHASE DIAGRAM OF UAs0.75Se0.25 SINGLE CRYSTAL

1988 ◽  
Vol 49 (C8) ◽  
pp. C8-479-C8-480 ◽  
Author(s):  
M. Kuznietz ◽  
P. Burlet ◽  
J. Rossat-Mignod ◽  
O. Vogt ◽  
K. Mattenberger ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Neutron Diffraction ◽  
Single Crystal ◽  
Magnetic Phase ◽  
Magnetic Phase Diagram ◽  
Magnetization Study

Single crystal neutron diffraction studies of antiferromagnets at low temperatures in applied magnetic fields

1959 ◽  
Vol 20 (2-3) ◽  
pp. 180-184 ◽  
Author(s):  
W.C. Koehler ◽  
M. K. Wilkinson ◽  
J.W. Cable ◽  
E.O. Wollan
Keyword(s):  
Magnetic Fields ◽  
Neutron Diffraction ◽  
Single Crystal ◽  
Low Temperatures

Water Molecule Dispositions in the Cesium Sulfate α- and β-Alums: Single-Crystal Neutron Diffraction Studies of CsM(SO4)2.12H2O (M=V, Rh)

1993 ◽  
Vol 46 (9) ◽  
pp. 1337 ◽  
Author(s):  
JK Beattie ◽  
SP Best ◽  
FH Moore ◽  
BW Skelton ◽  
AH White
Keyword(s):  
Neutron Diffraction ◽  
Water Molecule ◽  
Single Crystal ◽  
Tilt Angle ◽  
Room Temperature ◽  
Bond Angle ◽  
Sulfate Salt ◽  
Cell Dimensions ◽  
Coordinated Water ◽  
Unit Cell Dimensions

Room-temperature single-crystal neutron diffraction studies are recorded for two alums, Cs( Rh /V)(SO4)2.12H2O [cubic, Pa3, a 12.357(5) ( Rh ), 12.434(1)Ǻ (V)], residuals 0.037 and 0.068 for 328 and 164 'observed' reflections, with the intention of defining water molecule hydrogen atom orientations. Whereas the two tervalent hexaaqua cations are similar in size [ rM -O = 2.010(6)Ǻ (M = V) and 2.006(2)Ǻ (M = Rh )] the vanadium salt adopts the β alum modification while rhodium gives an α alum. Significantly, the water coordination geometry is different in the two cases with the tilt angle between the plane of the water molecule and the M-O bond vector being 1° (M = V) and 35° (M = Rh ). The tilt angle for water coordinated to rhodium in CsRh (SeO4)2.12H2O is inferred from the unit cell dimensions to be similar to that of the corresponding sulfate salt and not that which generally pertains for caesium selenate alums. Significant differences in the H-O-H bond angle are found for trigonal planar and trigonal pyramidal water coordination, suggesting that differences in the metal(III)-water interaction are a determinant of the geometry of the coordinated water molecule in the caesium sulfate/ selenate alum lattices.

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