Free-Standing Porous Silicon Film Produced by a Pulsed Anodic Etching of n+-Silicon Substrate in an HF: HCl: C2H5 OH: H2O2:H2O Electrolyte: Characterization and Adsorption of Colchicine

Silicon ◽  
2020 ◽  
Author(s):  
M. Naddaf ◽  
R. A. Jarjour
Author(s):  
Gyoko Nagayama ◽  
Ryuji Ando ◽  
Kei Muramatsu ◽  
Takaharu Tsuruta

We applied the anodic etching (i. e. photo assisted electrochemical etching) to the n type silicon substrate of orientation (100) without masking to fabricate macropores penetrated Si substrate. The anodic etching conditions of the macroporous formation were discussed and the effects of the resistivity, voltage, current density, electrolyte concentration and illumination etc. on the pore size and the porosity were investigated. The pores in high aspect ratio through the cross section of the silicon wafer were obtained with polishing and RIE (reactive ion etching) from the back side. It is found that the pore size at the back side is about 1.5 to 2 times larger than that of the front side. Also, as one example of the applications of porous silicon to microsystems, we demonstrate the results obtained in a micro fuel cell system using a porous silicon membrane (PSM). The PSM was fabricated by a porous silicon wafer which was filled with Nafion dispersion solution with ultrasonic vibrations. It was used as a proton conduction membrane by assembling into the H2 / air feed fuel cell at ambient conditions using conventional electrodes. We found that the Nafion filled PSM worked well and a maximum power density of 89.2 mW/cm2 were achieved under the flow rate of 100ml/min for H2 and 200ml/min for air.


2007 ◽  
Vol 7 (11) ◽  
pp. 4165-4168
Author(s):  
Jihoon Kim ◽  
Youngdae Koh ◽  
Seunghyun Jang ◽  
Young Chun Ko ◽  
Hee-Gweon Woo ◽  
...  

Well defined 1-dimentional (1-D) photonic crystals of polymer replicas have been successfully obtained. DBR porous silicon containing nanometer-scale pores are prepared by an anodic electrochemical etch of p++-type silicon wafer. The resulting DBR porous silicon film removed from the substrate by applying an electropolishing current has been thermally oxidized in the furnace at 400 °C for 3 h. Oxidized DBR PSi/polystyrene composite films are prepared by casting of polymer solution onto a free-standing porous silicon photonic crystal layer. Flexible photonic polymer replicas have been prepared after the removal of oxidized DBR PSi matrix in HF/H2O mixture solution. Polymer replicas exhibit a sharp resonance in the reflectivity spectrum. Optical characteristics of photonic polymer replica indicate that the surface of polymer film has a negative structure of DBR PSi. This replica is stable in aqueous solutions for several days without any degradation.


2004 ◽  
Vol 832 ◽  
Author(s):  
V. Agarwal ◽  
J.A. Soto Urueta ◽  
J. Miguel Gracia

ABSTRACTIn this paper we report the fabrication and experimental characterization of photoluminescent coupled multiple microcavity 1-Dimensional photonic bandgap structures for specific photonic applications. These structures have been prepared on silicon substrate as well as free standing. The comparision with theory gave a good fit showing desired structure formation for more than 184 layered structure. These structures can be useful for a large variety of applications such as silicon lasers.


2007 ◽  
Vol 7 (11) ◽  
pp. 4165-4168 ◽  
Author(s):  
Jihoon Kim ◽  
Youngdae Koh ◽  
Seunghyun Jang ◽  
Young Chun Ko ◽  
Hee-Gweon Woo ◽  
...  

Well defined 1-dimentional (1-D) photonic crystals of polymer replicas have been successfully obtained. DBR porous silicon containing nanometer-scale pores are prepared by an anodic electrochemical etch of p++-type silicon wafer. The resulting DBR porous silicon film removed from the substrate by applying an electropolishing current has been thermally oxidized in the furnace at 400 °C for 3 h. Oxidized DBR PSi/polystyrene composite films are prepared by casting of polymer solution onto a free-standing porous silicon photonic crystal layer. Flexible photonic polymer replicas have been prepared after the removal of oxidized DBR PSi matrix in HF/H2O mixture solution. Polymer replicas exhibit a sharp resonance in the reflectivity spectrum. Optical characteristics of photonic polymer replica indicate that the surface of polymer film has a negative structure of DBR PSi. This replica is stable in aqueous solutions for several days without any degradation.


2006 ◽  
Vol 20 (01) ◽  
pp. 99-110 ◽  
Author(s):  
V. AGARWAL ◽  
J. A. DEL RÍO

In this paper we report the detailed fabrication and experimental characterization of porous silicon one-dimensional photonic bandgap structures for specific photonic applications. These structures have been prepared on silicon substrate as well as free standing and can be proven useful for a large variety of applications such as high quality dielectric mirrors and filters.


2009 ◽  
Vol 11 (10) ◽  
pp. 105106 ◽  
Author(s):  
Georgiy V Tkachenko ◽  
Volodymyr Tkachenko ◽  
Luca De Stefano ◽  
Igor A Sukhoivanov

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