Origin of rare earth element anomalies in mangrove sediments, Sepetiba Bay, SE Brazil: used as geochemical tracers of sediment sources

Abstract The sediment sources in the southern Okinawa trough (SOT) are still controversial and few studies have focused on the effects of transport processes on the elemental composition of initial terrigenous materials. Here we present rare earth element (REE) and trace element data on siliciclastic sediments from 14C age-dated Core S3, which was collected from the SOT, to provide reliable evidence for illustrating the modified effects of marine environments on terrigenous sediments deposited at different stages and exposing changes in sediment source over the past 3 ka. Compared with bulk sediments, the siliciclastic sediments in S3 have more variable REE fractionation parameters and lower middle REE (MREE) contents. Our REE data indicate that during river-sea processes, MREE-enriched fractions such as Fe–Mn oxides and carbonate were added to the original terrigenous sediments before deposition, weakening the degree of REE fractionation in the initial sediments; thus, care should be taken when using REE data from bulk samples to decipher source changes. The temporal changes in sediment source in S3 can be broadly identified based on the REE fractionation parameters of the residual fractions, and the results are largely consistent with the findings obtained by heavy mineral examinations. Units 1 and 3 are dominated by reworked shelf sediments of Changjiang origin,while the proportion of Taiwan-derived sediment is notably higher in Units 2 and 4. The sediment flux of Taiwan origin in the SOT was much smaller than previously thought. Huanghe-derived sediments and volcanic materials did not contribute significantly to the late Holocene sedimentation in the SOT. The large variations in sediment sources in S3 were possibly caused by changes in transport patterns driven by time-dependent changes in oceanic currents.

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Natural and Anthropogenic Geochemical Tracers to Investigate Residence Times and Groundwater–Surface-Water Interactions in an Urban Alluvial Aquifer

Water ◽

10.3390/w13060871 ◽

2021 ◽

Vol 13 (6) ◽

pp. 871

Author(s):

Connor P. Newman ◽

Suzanne S. Paschke ◽

Gabrielle Keith

Keyword(s):

Rare Earth ◽

Surface Water ◽

Rare Earth Element ◽

Earth Element ◽

Flow System ◽

Alluvial Aquifer ◽

Residence Times ◽

Geochemical Tracers ◽

Recharge Sources ◽

Wastewater Indicator

A multi-component geochemical dataset was collected from groundwater and surface-water bodies associated with the urban Fountain Creek alluvial aquifer, Colorado, USA, to facilitate analysis of recharge sources, geochemical interactions, and groundwater-residence times. Results indicate that groundwater can be separated into three distinct geochemical zones based on location within the flow system and proximity to surface water, and these zones can be used to infer sources of recharge and groundwater movement through the aquifer. Rare-earth-element concentrations and detections of wastewater-indicator compounds indicate the presence of effluent from wastewater-treatment plants in both groundwater and surface water. Effluent presence in groundwater indicates that streams in the area lose to groundwater in some seasons and are a source of focused groundwater recharge. Distributions of pharmaceuticals and wastewater-indicator compounds also inform an understanding of groundwater–surface-water interactions. Noble-gas isotopes corroborate rare-earth-element data in indicating geochemical evolution within the aquifer from recharge area to discharge area and qualitatively indicate variable groundwater-residence times and mixing with pre-modern groundwater. Quantitative groundwater-residence times calculated from 3H/3He, SF6, and lumped-parameter modeling generally are less than 20 years, but the presence of mixing with older groundwater of an unknown age is also indicated at selected locations. Future investigations would benefit by including groundwater-age tracers suited to quantification of mixing for both young (years to decades) and old (centuries and millennia) groundwater. This multi-faceted analysis facilitated development of a conceptual model for the investigated groundwater-flow system and illustrates the application of an encompassing suite of analytes in exploring hydrologic and geochemical interactions in complex systems.

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