scholarly journals Author Correction: Alkaline Ethanol Oxidation Reaction on Carbon Supported Ternary PdNiBi Nanocatalyst using Modified Instant Reduction Synthesis Method

2020 ◽  
Vol 12 (1) ◽  
pp. 101-102
Author(s):  
Bernd Cermenek ◽  
Boštjan Genorio ◽  
Thomas Winter ◽  
Sigrid Wolf ◽  
Justin G. Connell ◽  
...  
Keyword(s):  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Synthesis Method ◽  
Ethanol Oxidation Reaction

scholarly journals Alkaline Ethanol Oxidation Reaction on Carbon Supported Ternary PdNiBi Nanocatalyst using Modified Instant Reduction Synthesis Method

2020 ◽  
Vol 11 (2) ◽  
pp. 203-214
Author(s):  
Bernd Cermenek ◽  
Boštjan Genorio ◽  
Thomas Winter ◽  
Sigrid Wolf ◽  
Justin G. Connell ◽  
...  
Keyword(s):  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Synthesis Method ◽  
Compositional Analysis ◽  
Rotating Disk ◽  
Rotating Disk Electrode ◽  
The Other ◽  
Ethanol Oxidation Reaction ◽  
Direct Ethanol Fuel Cells ◽  
Onset Potential

AbstractDirect ethanol fuel cells (DEFC) still lack active and efficient electrocatalysts for the alkaline ethanol oxidation reaction (EOR). In this work, a new instant reduction synthesis method was developed to prepare carbon supported ternary PdNiBi nanocatalysts with improved EOR activity. Synthesized catalysts were characterized with a variety of structural and compositional analysis techniques in order to correlate their morphology and surface chemistry with electrochemical performance. The modified instant reduction synthesis results in well-dispersed, spherical Pd85Ni10Bi5 nanoparticles on Vulcan XC72R support (Pd85Ni10Bi5/C(II-III)), with sizes ranging from 3.7 ± 0.8 to 4.7 ± 0.7 nm. On the other hand, the common instant reduction synthesis method leads to significantly agglomerated nanoparticles (Pd85Ni10Bi5/C(I)). EOR activity and stability of these three different carbon supported PdNiBi anode catalysts with a nominal atomic ratio of 85:10:5 were probed via cyclic voltammetry and chronoamperometry using the rotating disk electrode method. Pd85Ni10Bi5/C(II) showed the highest electrocatalytic activity (150 mA⋅cm−2; 2678 mA⋅mg−1) with low onset potential (0.207 V) for EOR in alkaline medium, as compared to a commercial Pd/C and to the other synthesized ternary nanocatalysts Pd85Ni10Bi5/C(I) and Pd85Ni10Bi5/C(III). This new synthesis approach provides a new avenue to developing efficient, carbon supported ternary nanocatalysts for future energy conversion devices.

Surfactant-Free Synthesis of PdPt/rGO for the Alkaline Ethanol Oxidation Reaction

NANO ◽  
2017 ◽  
Vol 12 (09) ◽  
pp. 1750105 ◽  
Author(s):  
Meiling Peng ◽  
Tao Wang ◽  
Zhenzhen Jiang ◽  
Sheng Wang
Keyword(s):  
Catalytic Activity ◽  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Uv Light ◽  
Synthesis Method ◽  
Active Surface ◽  
Alkaline Media ◽  
Active Surface Area ◽  
Ethanol Oxidation Reaction ◽  
Direct Alcohol Fuel Cells

In this work, a synthesis method of residue-free PdPt nanodendrites on reduced graphene oxide (rGO) is reported. Using UV light as an energy trigger and methanol as the reducing agent, PdPt nanodendrites are synthesized with clean, residue-free surfaces (e.g., surfactant and polymer). In comparison with commercial Pd/C and Pt/C catalysts, the as-prepared PdPt nanodendrites on rGO have a large electrochemically active surface area, enhanced catalytic activity, high stability, and tolerance toward the ethanol oxidation reaction in alkaline media. Among the nanodendrite composites prepared, those containing a Pd:Pt ratio of 1:2 on rGO exhibit the best stability and durability, and their mass activity is 2.0 and 2.4 times greater than those of commercial Pt/C and Pd/C catalysts, respectively. This strategy presents an environmentally friendly way to fabricate other noble metal catalysts with improved catalytic activity and stability for use in direct alcohol fuel cells.

Ultrafine FePd Nanoalloys Decorated Multiwalled Cabon Nanotubes toward Enhanced Ethanol Oxidation Reaction

2015 ◽  
Vol 7 (43) ◽  
pp. 23920-23931 ◽  
Author(s):  
Yiran Wang ◽  
Qingliang He ◽  
Jiang Guo ◽  
Jinmin Wang ◽  
Zhiping Luo ◽  
...  
Keyword(s):  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Ethanol Oxidation Reaction

Ethanol Oxidation Reaction Using PtSn/C+Ce/C Electrocatalysts: Aspects of Ceria Contribution

2014 ◽  
Vol 117 ◽  
pp. 292-298 ◽  
Author(s):  
R.F.B. De Souza ◽  
J.C.M. Silva ◽  
M.H.M.T. Assumpção ◽  
A.O. Neto ◽  
M.C. Santos
Keyword(s):  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Ethanol Oxidation Reaction

scholarly journals Ternary Pt/Re/SnO2 nanoparticles for ethanol oxidation reaction: Understanding the correlation between the synthesis route and the obtained material

2019 ◽  
Vol 570 ◽  
pp. 319-328 ◽  
Author(s):  
Magdalena Parlinska-Wojtan ◽  
Elżbieta Drzymała ◽  
Grzegorz Gruzeł ◽  
Joanna Depciuch ◽  
Mikołaj Donten ◽  
...  
Keyword(s):  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Sno2 Nanoparticles ◽  
Ethanol Oxidation Reaction ◽  
Synthesis Route

A perspective on the promoting effect of Ir and Au on Pd toward the ethanol oxidation reaction in alkaline media

2018 ◽  
Vol 12 (4) ◽  
pp. 501-508 ◽  
Author(s):  
S. Y. Shen ◽  
Y. G. Guo ◽  
G. H. Wei ◽  
L. X. Luo ◽  
F. Li ◽  
...  
Keyword(s):  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Alkaline Media ◽  
Ethanol Oxidation Reaction ◽  
Promoting Effect

scholarly journals Facile Synthesis of Pd@PtM (M = Rh, Ni, Pd, Cu) Multimetallic Nanorings as Efficient Catalysts for Ethanol Oxidation Reaction

2021 ◽  
Vol 9 ◽  
Author(s):  
Xingqiao Wu ◽  
Xiao Li ◽  
Yucong Yan ◽  
Sai Luo ◽  
Jingbo Huang ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Epitaxial Growth ◽  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Hollow Structure ◽  
Ethanol Oxidation Reaction ◽  
Hollow Nanostructures ◽  
Oxidative Etching ◽  
General Method

Pt-based multimetallic nanorings with a hollow structure are attractive as advanced catalysts due to their fantastic structure feature. However, the general method for the synthesis of such unique nanostructures is still lack. Here we report the synthesis of Pd@PtM (M = Rh, Ni, Pd, Cu) multimetallic nanorings by selective epitaxial growth of Pt alloyed shells on the periphery of Pd nanoplates in combination with oxidative etching of partial Pd in the interior. In situ generation of CO and benzoic acid arising from interfacial catalytic reactions between Pd nanoplates and benzaldehyde are critical to achieve high-quality Pt-based multimetallic nanorings. Specifically, the in-situ generated CO promotes the formation of Pt alloyed shells and their epitaxial growth on Pd nanoplates. In addition, the as-formed benzoic acid and residual oxygen are responsible for selective oxidative etching of partial Pd in the interior. When evaluated as electrocatalysts, the Pd@PtRh nanorings exhibit remarkably enhanced activity and stability for ethanol oxidation reaction (EOR) compared to the Pd@PtRh nanoplates and commercial Pt/C due to their hollow nanostructures.

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