Synchronously improved wave-transparent performance and mechanical properties of cyanate ester resins via introducing fluorine-containing linear random copolymer

Author(s):  
Yuxiao Zhou ◽  
Junliang Zhang ◽  
Chang Qu ◽  
Liangchen Li ◽  
Jie Kong ◽  
...  
2017 ◽  
Vol 5 (28) ◽  
pp. 6929-6936 ◽  
Author(s):  
Junwei Gu ◽  
Wencai Dong ◽  
Yusheng Tang ◽  
Yongqiang Guo ◽  
Lin Tang ◽  
...  

Ultralow dielectric constant, prominent mechanical properties, and high thermal and dimension stabilities were achieved in cyanate ester resins copolymerized with fluoride-containing epoxy groups.


Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 201 ◽  
Author(s):  
Zhifei Chen ◽  
Shuxin Li ◽  
Yuwei Shang ◽  
Shan Huang ◽  
Kangda Wu ◽  
...  

A random copolymer of isobutylene (IB) and 4-vinylbenzenecyclobutylene (4-VBCB) was synthesized by cationic polymerization at −80 °C using 2-chloro-2,4,4-trimethylpentane (TMPCl) as initiator. The laws of copolymerization were investigated by changing the feed quantities of 4-VBCB. The molecular weight of the copolymer decreased, and its molecular weight distribution (MWD) increased with increasing 4-VBCB content. We proposed a possible copolymerization mechanism behind the increase in the chain transfer reaction to 4-VBCB with increasing of feed quantities of 4-VBCB. The thermal properties of the copolymers were studied by solid-phase heating and crosslinking. After crosslinking, the decomposition and glass transition temperatures (Tg) of the copolymer increased, the network structure that formed did not break when reheated, and the mechanical properties remarkably improved.


Polymer ◽  
2018 ◽  
Vol 148 ◽  
pp. 14-26 ◽  
Author(s):  
A. Vashchuk ◽  
A. Rios de Anda ◽  
O. Starostenko ◽  
O. Grigoryeva ◽  
P. Sotta ◽  
...  

2021 ◽  
pp. 48-60
Author(s):  
E.V. Dolgova ◽  
◽  
K.S. Lavrova ◽  

The review concerns the major application of materials based on cyanate ester resins in various branches of technology, indicating examples of implementation in modern devices. This article being the first part of the review highlights the cyanate esters implementation in the development of materials for aviation and space technology. The paper presents the most significant properties of polycyanurates in relation to their application. Information about the development of new cyanate ester resin-based composite materials for aircrafts and space shuttles is provided.


2015 ◽  
Vol 38 (3) ◽  
pp. 523-527 ◽  
Author(s):  
Yiqun Wang ◽  
Kaichang Kou ◽  
Longhai Zhuo ◽  
Guanglei Wu

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