Spectrofluorimetric flow injection determination of adrenaline with an iodine solid-phase reactor

1995 ◽  
Vol 308 (1-3) ◽  
pp. 334-338 ◽  
Author(s):  
A. Kojło ◽  
J.Martínez Calatayud
Keyword(s):  
Flow Injection ◽  
Solid Phase ◽  
Solid Phase Reactor

Determination of Bendiocarb Insecticide by Reverse Flow Injection Analysis Using a Solid-Phase Reactor Containing Micro PbO2, Nano PbO2 and Grafted SiO2 - PbO2 Immobilized

2020 ◽  
Vol 42 (1) ◽  
pp. 31-31
Author(s):  
Malik H Alaloosh Alamri Malik H Alaloosh Alamri ◽  
Sadeem Subhi Abed and Abdulkareem M A Alsammarraie Sadeem Subhi Abed and Abdulkareem M A Alsammarraie
Keyword(s):  
Flow Injection ◽  
Limit Of Detection ◽  
Solid Phase ◽  
Reverse Flow ◽  
Blue Color ◽  
Wide Range ◽  
Solid Phase Reactor ◽  
Grafted Nanoparticles ◽  
Reverse Flow Injection

Bendiocarb (BEN) is an acutely toxic carbamate insecticide which used in public places and agriculture, it is also effective against a wide range of nuisance and disease vector insects. A new rapid and sensitive reverse flow injection spectrophotometric procedure coupled with on-line solid-phase reactor is designed in this article for the determination of BEN in its insecticidal formulations and water samples, by using three different solid-phase reactors containing bulk PbO2 (B-SPR), PbO2 nanoparticles (N-SPR) and grafted nanoparticles of SiO2-PbO2 (G-SPR) immobilized on cellulose acetate matrix (CA). This method of oxidative coupling is based on alkaline hydrolysis of the BEN pesticide, and then coupled with N,N dimethyl-p-phenylenediamine sulphate (DMPD) to give a blue color product which measured at λmax 675 nm. It worth to mentioned that under optimal conditions, Beer’s law is obeyed in the range of 1-175 μg mL-1 for B-SPR and 0.25-70 μg mL-1 of BEN for both N-SPR and G-SPR respectively within limit of detection (LOD) of 0.931, 0.234 and 0.210 μg mL-1 for B-SPR N-SPR and G-SPR respectively. The surface methodology of the solid phase was also investigated by using atomic force microscopy.

scholarly journals DETERMINATION OF NITRAZEPAM IN PHARMACEUTICAL PREPARATIONS USING SOLID-PHASE REACTOR - REVERSE FLOW INJECTION ANALYSIS

2018 ◽  
Vol 11 (7) ◽  
pp. 487
Author(s):  
Mariam Jamal ◽  
Hind Hadi
Keyword(s):  
Flow Injection ◽  
Solid Phase ◽  
Reverse Flow ◽  
Injection System ◽  
Physical Parameters ◽  
Relative Standard ◽  
Solid Phase Reactor ◽  
Oxidation Reactor ◽  
Reverse Flow Injection

Objective: A simple and fast reverse flow injection system including a solid-phase reactor containing PbO2 with spectrophotometric detection was suggested for the determination of nitrazepam (NIT) in pharmaceutical tablets.Methods: The method was based on oxidation of the reagent (phloroglucinol) with PbO2 immobilized in a polymeric matrix which was then coupled with reduced NIT in aqueous medium. The pink-colored product was measured at 530 nm.Results: The calibration graph was linear over the range of 50–400 μg/mL with a relative standard deviation of <2% (n=29) and a sample throughput of 48 samples per hour. The variables of the solid-phase reactor such as composition, particle size, and length of the reactor were studied. The chemical and physical parameters, which affect the reverse flow method, were also studied.Conclusion: The oxidation reactor engaged with a flow system was successfully applied for the determination of NIT with good sensitivity and precision.

scholarly journals Flow-injection spectrophotometric determination of captopril in pharmaceutical formulations using a new solid-phase reactor containing AgSCN immobilized in a polyurethane resin

2012 ◽  
Vol 48 (2) ◽  
pp. 325-333 ◽  
Author(s):  
Fernando Campanhã Vicentini ◽  
Willian Toito Suarez ◽  
Éder Tadeu Gomes Cavalheiro ◽  
Orlando Fatibello-Filho
Keyword(s):  
Flow Injection ◽  
Solid Phase ◽  
Pharmaceutical Formulations ◽  
Analysis Procedure ◽  
Polyurethane Resin ◽  
Analytical Curve ◽  
Relative Standard ◽  
Solid Phase Reactor ◽  
Simple Flow

A simple flow-injection analysis procedure was developed for determining captopril in pharmaceutical formulations employing a novel solid-phase reactor containing silver thiocyanate immobilized in a castor oil derivative polyurethane resin. The method was based on silver mercaptide formation between the captopril and Ag(I) in the solid-phase reactor. During such a reaction, the SCN- anion was released and reacted with Fe3+, which generated the FeSCN2+ complex that was continuously monitored at 480 nm. The analytical curve was linear in the captopril concentration range from 3.0 × 10-4 mol L-1 to 1.1 × 10-3 mol L-1 with a detection limit of 8.0 × 10-5 mol L-1. Recoveries between 97.5% and 103% and a relative standard deviation of 2% for a solution containing 6.0 × 10-4 mol L-1 captopril (n = 12) were obtained. The sample throughput was 40 h-1 and the results obtained for captopril in pharmaceutical formulations using this procedure and those obtained using a pharmacopoeia procedure were in agreement at a 95% confidence level.

Flow-Injection Spectrophotometric Determination of Captopril Exploiting Silver Chloranilate Solid-Phase Reactor

2009 ◽  
Vol 42 (7) ◽  
pp. 973-988 ◽  
Author(s):  
Willian Toito Suarez ◽  
Viviane Gomes Bonifácio ◽  
Alexandro Alves Madi ◽  
Orlando Fatibello-Filho
Keyword(s):  
Spectrophotometric Determination ◽  
Flow Injection ◽  
Solid Phase ◽  
Solid Phase Reactor
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