Hardened portland cement pastes of low porosity III. Degree of hydration. Expansion of paste. Total porosity

1972 ◽  
Vol 2 (4) ◽  
pp. 463-480 ◽  
Author(s):  
Ivan Odler ◽  
Marvin Yudenfreund ◽  
Jan Skalny ◽  
Stephen Brunauer
1973 ◽  
Vol 3 (3) ◽  
pp. 279-293 ◽  
Author(s):  
Stephen Brunauer ◽  
Jan Skalny ◽  
Ivan Odler ◽  
Marvin Yudenfreund

1972 ◽  
Vol 2 (5) ◽  
pp. 577-589 ◽  
Author(s):  
Ivan Odler ◽  
Julius Hagymassy ◽  
Edward E. Bodor ◽  
Marvin Yudenfreund ◽  
Stephen Brunauer

1972 ◽  
Vol 2 (6) ◽  
pp. 731-743 ◽  
Author(s):  
Marvin Yudenfreund ◽  
Kaissar M. Hanna ◽  
Jan Skalny ◽  
Ivan Older ◽  
Stephen Brunauer

1973 ◽  
Vol 3 (2) ◽  
pp. 129-147 ◽  
Author(s):  
Stephen Brunauer ◽  
Marvin Yudenfreund ◽  
Ivan Odler ◽  
Jan Skalny

1991 ◽  
Vol 245 ◽  
Author(s):  
Bruce J. Christensen ◽  
Thomas O. Mason ◽  
Hamlin M. Jennings

ABSTRACTMeasurements of the bulk electrical properties of cement pastes were made using impedance spectroscopy (IS) and are useful for studying hydration. Normalization of these quantities by dividing out changes in the pore fluid reveals information pertinent to the microstructural development of these materials. In this study, observations are made on the influence of accelerators, retarders and silica fume (SF) on pastes of white and ordinary portland cements (OPC). All systems show variations in the normalized electrical properties at the same degree of hydration, as compared to a control. Changes in the microstructure that are implied by these measurements are consistent with the observations of others.


1993 ◽  
Vol 23 (2) ◽  
pp. 399-406 ◽  
Author(s):  
J.E. Ash ◽  
M.G. Hall ◽  
J.I. Langford ◽  
M. Mellas

2008 ◽  
Vol 14 (4) ◽  
pp. 269-275 ◽  
Author(s):  
Z’hor Guemmadi ◽  
Musa Resheidat ◽  
Hacéne Houari ◽  
Belkacem Toumi

The effect of substitution of Portland cement by limestone up to 40% as well as its fineness on the physico‐mechanical properties of fresh and hardened cement pastes is studied. The binder was prepared by substitution of cement by limestone filler. Fillers were chosen of various particle sizes and with percentages from 5 to 40. Test results revealed that the replacement of Portland cement by the finest filler of limestone slightly decreases the consistency and the setting times (initial and final). The total porosity decreases and accordingly the compressive strength is improved with the content and fines of limestone. Although limestone has a little accelerating effect on the hydration process of Portland cement, but acts only as a filler reducing the porosity due to its compact structure, in which the compressive strength of the hardened cement paste is enhanced. The XRD and DTA analyses of samples cured up to 28 days showed that this amelioration is due to formation of new hydrated compounds. It is concluded that an addition of finely ground limestone filler only up to 15% gives a better strength. Santrauka Tirtos šviežios ir sukietėjusios cementinės tešlos, kurioje iki 40 % cemento pakeista įvairaus smulkumo maltu kalkakmeniu, savybės. Rišiklis buvo paruoštas dalį cemento pakeitus maltu kalkakmenio užpildu. Užpildo dalelės buvo įvairaus dydžio, o jų kiekis buvo keičiamas nuo 5 % iki 40 %. Tyrimai parodė, kad priedas leidžia sumažinti vandens kiekį, reikalingą tos pačios konsistencijos mišiniui gauti, taip pat cemento rišimosi pradžiai ir pabaigai paankstinti. Sumažėja cementinio akmens suminis poringumas ir atitinkamai padidėja stipris gniuždant cementinio akmens, kuriame yra kalkakmenio priedų. Nors kalkakmenio priedas nedaug pagreitina portlandcemenčio hidratacijos procesą, tačiau veikia kaip užpildas, sutankinantis struktūrą, dėl to labai padidėja sukietėjusio cementinio akmens stipris gniuždant. Bandinių, išlaikytų 28 dienas, rentgenostruktūrinė ir diferencinė terminė analizė parodė, kad pagerėjimas yra dėl susidariusių naujadarų. Apibendrinant galima teigti, kad 15 % malto kalkakmenio priedas turi didžiausią įtaką stiprumo rezultatams.


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