Absolute Age Determination: Physical and Chemical Dating Methods and Their Application

1991 ◽  
Vol 55 (6) ◽  
pp. 1751
Author(s):  
Leon E. Long
Author(s):  
Norman Herz ◽  
Ervan G. Garrison

Time is nature's way of keeping everything from happening at once" (anonymous). Time is a continuum—we sense this continuum as a succession of events. In archaeological matters it is one of the most salient attributes. To determine time accurately the archaeologist must rely on modern dating techniques. Age determination by chemical methods relies on the constancy or predictability of rates of chemical processes. For instance the oxidation of iron—rust—could be used for dating purposes if one could determine a chemical rate, in this case that of oxidation, that applied to more than the singular event. Unfortunately, the rate of the oxidation of iron is highly variable, being affected by temperature, available moisture, and the particular type of iron (mild, cast, stainless, etc.). Another common chemical change is the patination of certain types of glass. Yet here, too, the process is highly variable, making dating impractical. Still, there have been attempts to use patination and rock "varnish" for archaeological dating, as we shall see. In the main, chemical dating is used to determine relative ages since absolute ages require calibration for each sample and its find site using independent dating measures such as radiometric or dendrochronological techniques. We shall first discuss the relative techniques based on the uptake or decrease in fluorine, uranium, and nitrogen found in bone. This is most appropriate because these chemical techniques played a key role in unmasking one of the most famous frauds in the history of science: Piltdown Man. Next we shall examine the two most accepted chemical processes utilized in absolute age determination, which are based, respectively, on amino acid racemization and obsidian hydration. Finally, we shall examine a few techniques that show some promise for the dating of archaeological materials or deposits, such as those using patination ("varnish") and cation ratios. Our points of reference are those events we view as, in some sense, marking a change in the state of things. Stylistic or formal change in an archaeological facies can be a chronological landmark for the archaeologist and allows us to divide the continuum of time into discrete segments or phases.


Author(s):  
Andrew S. Cohen

It is almost impossible to overemphasize the importance of good chronological control to paleolimnology. Age control allows us to determine rates of processes and fluxes of materials, and to test hypotheses of linkage between archives and hypothesized external controls of those archives. Geologists differentiate between relative age versus absolute dating methods. Relative age determinations are based on the concepts of superposition (older sediments are on the bottom, in the absence of tectonic disturbance) and lithological correlation. In contrast, absolute dating methods are done without necessary reference to other analyses or locations, to produce an age determination (i.e., 100,000 yr before present). Some methods, such as paleomagnetics, amino acid racemization, and biostratigraphy, lie in a gray area between these two, providing absolute dates or age ranges in certain circumstances and relative age constraints in others. In this book, I will refer to the general study of both relative and absolute age determination as geochronology, and use the term geochronometry to refer to absolute dating. Lithological correlation involves matching similar lithologies between outcrop or core localities, allowing a network of age relationships to be established between various sites. This can be done at any scale, from within a lake to intercontinental, although lithostratigraphical correlations based on core or outcrop observations are most commonly useful only at a local, intrabasinal level. Correlation within basins is often achieved using reflection seismic stratigraphy. Depositional or unconformity surfaces can normally be recognized on seismic lines that extend over the scale of individual sub-basins to entire lakes (Nelson et al., 1994; Lezzar et al., 1996; Van Rensbergen et al., 1998). When dated cores are obtained or outcrops studied along these seismic lines, a correlation network can be established, with probable ages attached to specific seismic horizons. Intrabasinal correlation can also be done by correlating distinctive patterns of change in features such as magnetic intensity, patterns of stable isotopic change in sediments, or biostratigraphical markers, that may be consistent across a lake basin. Sometimes, relative correlations can be made between lakes.


From time to time, it is desirable to review a given field of research, its methods and accomplishments, and see what further advances in that field may be anticipated. Toward this end, physical and chemical dating methods applicable to anthropological and archaeological problems are reviewed and discussed here, particularly recent innovations, followed by a discussion of the present status of established calibration points in early hominid evolution.


1983 ◽  
Vol 40 (9) ◽  
pp. 1430-1441 ◽  
Author(s):  
W. D. Bowen ◽  
D. E. Sergeant ◽  
T. Øritsland

We investigated the validity and accuracy of age estimation in harp seals, Phoca groenlandica, using a sample of 155 known-age teeth from seals age 3 mo to 10 yr. Under transmitted light, transverse sections of harp seal canine teeth showed distinct incremental growth layers (IGLs) in the dentine. The first growth-layer group (GLG), representing Ist-year growth, consists of two IGLs: an outer layer of opaque dentine, bounded by the neonatal line, and an inner layer of translucent dentine. Subsequent GLGs, each representing 1 yr of growth, generally consist of three IGLs: an outer layer of interglobular dentine deposited during the annual molt in April, a middle layer of opaque dentine formed during the northward spring migration (May–June), and an inner layer of translucent dentine formed from July to March. We show that dentinal GLGs can be used to estimate the absolute age of harp seals. The accuracy of the method decreases with age. Only 72.4% of estimates of 0-group seals were correct using only transverse sections. These errors were virtually eliminated (99.0% correct age determination) when the tooth root was examined. Based on a single examination of a transverse section, the probabilities of correctly estimating age are 0.983, 0.889, 0.817, and 0.553 at ages 1, 2, 3, and 4 + yr, respectively, when clearly inaccurate tag-tooth associations are omitted. The respective probabilities are only slightly higher when age is based on the average of five blind readings, being 1.0, 0.889, 0.833, and 0.625. Beyond age 3 yr, existing data are insufficient to estimate reliably the accuracy of age determined by counting GLGs.


2021 ◽  
Author(s):  
Moska Piotr ◽  
Sokołowski Robert ◽  
Jary Zdzisław ◽  
Zieliński Paweł ◽  
Raczyk Jerzy ◽  
...  

<p>Multi-proxy studies (including sedimentological, pedological, radiocarbon and optically stimulated luminescence dating methods) were used to establish origin and chronology of depositional processes in the type section Mierzyn, central Poland. The investigated key site is located in the extraglacial zone of the Last Glaciation, ca. 130 km to the south from the Last Glacial Maximum in the Luciąża river valley area. In the studied profile (16 m thick) two lithofacial complexes were identified. The lower, fluvio-aeolian complex consists of silty-sandy sediments (1.6 m) deposited. The final phase of fluvio-aeolian deposition is expressed by initial pedogenic processes. Above is located aeolian complex (13 m of thickness). Three aeolian units are separated by two palaeosols.</p><p>To establish stratigraphic framework of depositional and pedogenic processes, four samples for radiocarbon dating from palaeosols and twelve samples for OSL dating from sandy units were collected. The obtained results reveal very good agreement of both absolute dating methods. It led to reconstruct chronology of main palaeoenvironmental changes. The fluvio-aeolian complex and the lowermost part of aeolian complex (below the lower palaeosol) were deposited in the Oldest Dryas in relatively cool and dry climate conditions. The amelioration of climate in the Bølling interstadial caused development of pedogenic processes expressed by 0.3 m thick palaeosol. Main part of aeolian complex (10 m of thickness) was deposited in the Older Dryas. The upper palaeosol developed in the Allerød interstadial as a result of the next amelioration of the climate. During the Younger Dryas was deposited the uppermost part of aeolian complex.</p><p>Classic development of fluvial to- aeolian succession in the Mierzyn site as well as detailed chronology based on two independent absolute age methods reveal that it can be treated as stratotype for the Late Glacial and correlated with other type sections in the Central and Western Europe.</p><p><strong>Ackowledgments</strong></p><p>Presented results were obtained with support of Polish National Science Centre, contract number 2018/30/E/ST10/00616.</p><p> </p>


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