Thermal constraints on crustal rare gas release and migration: Evidence from Alpine fluid inclusions

1994 ◽  
Vol 58 (20) ◽  
pp. 4333-4348 ◽  
Author(s):  
C.J Ballentine ◽  
M Mazurek ◽  
A Gautschi
2020 ◽  
pp. 014459872097451
Author(s):  
Wenqi Jiang ◽  
Yunlong Zhang ◽  
Li Jiang

A fluid inclusion petrographic and microthermometric study was performed on the sandstones gathered from the Yanchang Formation, Jiyuan area of the Ordos Basin. Four types of fluid inclusions in quartz can be recognized based on the location they entrapped. The petrographic characteristics indicate that fluid inclusions in quartz overgrowth and quartz fissuring-I were trapped earlier than that in quartz fissuring-IIa and fissuring-IIb. The homogenization temperature values of the earlier fluid inclusions aggregate around 80 to 90°C; exclusively, it is slightly higher in Chang 6 member, which approaches 95°C. The later fluid inclusions demonstrate high homogenization temperatures, which range from 100 to 115°C, and the temperatures are slightly higher in Chang 9 member. The calculated salinities show differences between each member, including their regression characteristics with burial depth. Combining with the vitrinite reflection data, the sequence and parameters of fluid inclusions indicate that the thermal history of the Yanchang formation mostly relied on burial. Salinity changes were associated with fluid-rock interaction or fluid interruption. Hydrocarbon contained fluid inclusions imply that hydrocarbon generation and migration occurred in the Early Cretaceous. The occurrence of late fluid inclusions implied that quartz cement is a reservoir porosity-loose factor.


2020 ◽  
Author(s):  
Bettina Strauch ◽  
Martin Zimmer ◽  
Axel Zirkler

<p>Fluid inclusions are voids enclosed in the rock matrix and contain, depending on their origin and development, various amounts of gaseous, liquid or solid phases. Depending on their occurrence within the crystalline structure or in healed micro-fractures, primary and secondary inclusions can be distinguished. Their characteristics are utilized in various geological settings to reconstruct rock history and fluid involvement. Fluid inclusions could also be considered to be small equivalents to large cavities. As salt is regarded a favorable host rock for the storage of natural gas and other materials in artificial caverns, knowledge on gas migration and retention is crucial.</p><p>Here, we present results of a fluid inclusion study in various salt rocks using Raman spectroscopy in addition to conventional microscopic characterization and gas analysis on whole rock samples. This approach allows for a better understanding of fluid generation and migration in different salt lithologies over geological times.</p><p>Various salt minerals (halite, sylvite, kieserite and carnallite) from an area of potential overprint of CO<sub>2</sub>-dominated gas migration were investigated. Numerous fluid inclusions exhibit chevron structure and are small sized. Large single- or two-phased inclusions are observed with irregular shapes, often indicative for leakage or necking down. Interestingly, although the CO<sub>2</sub> concentrations in whole rock samples were high, fluid inclusions were dominated by an aqueous phase and often contain numerous daughter minerals. This suggests that CO<sub>2</sub>-rich gas is stored along distinct fractures or grain boundaries within an otherwise intact rock.</p>


1996 ◽  
Vol 60 (2) ◽  
pp. 225-233 ◽  
Author(s):  
Stephen E. Kesler ◽  
Anna M. Martini ◽  
Martin S. Appold ◽  
Lynn M. Walter ◽  
Ted J. huston ◽  
...  

We present the results of a theoretical investigation of the trapping and migration of the fission gas atoms, Kr and Xe in UO 2 . Our models differ from those previously presented in discussions of rare gas diffusion in ionic crystals. We propose that trapping occurs at vacancy aggregates, and that detrapping into interstitial sites is unimportant; gas migration is effected by the intrinsic mobility of the gas-trap complexes. We suggest that the trapping and diffusion of the two gas atoms occur by different mechanisms, owing to their different sizes. Our results explain many of the observations of the experimental study of Felix & Miekeley and emphasize the importance of the chemical composition of the fuel on gas diffusion coefficients. The contradictions between this work and the earlier studies summarized by Matzke is, we suggest, possibly due to the higher levels of radiation damage which may have been present in the crystals used in the latter work.


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