The purpose of this work is the development of microcoulometric cell for measurement
of halogenide ions in the range of ng amounts. The main task in the innovation is to fulfil the need
of sensitive halogene determination in the automated measurement of the so-called adsorbable
organically bound halogens (AOX) in waters. The very low consumption of supporting electrolyte
and the energy saving configuration is also important factors in designing of monitor operation. We
developed a micro volume tube reactor, which can work continuously with peristaltic pumps
feeding the supporting electrolyte and the sample. The tube cell allows the injection of liquid and
gas samples without changing the cell construction. A three electrode type potentiostatic
microcoulometer with a rotating Ag working electrode was built, which maintains a constant
electrode potential of the working electrode to the reference electrode by the generation of silver
ions through anodic dissolution. The halogenide ions in sample solution change the electrode
potential of the working electrode. The potentiostatic controller circuit sets a current flowing
between the Ag working (anode) and a counter electrode (cathode). This current generates silver
ions from the working electrode, these ions precipitate the halogenide ions from the cell electrolyte
and restore the potential of the working electrode. It was a further successful hydraulic development
to achieve a microvolume cell, which accepts both gas and liquid samples in the same equipment.
The developed microcoulometer system has high sensitivity and works reliable in a wide measuring
range.
Effect of electrochemical parameters and working electrode material on the characteristics of bismuth (III) oxide obtained by electrodeposition and thermal oxidation