Electrochemical oxidation of adsorbed carbon monoxide on platinum spherical single crystals

1990 ◽  
Vol 294 (1-2) ◽  
pp. 97-110 ◽  
Author(s):  
A.M. de Becdelièvre ◽  
J. de Becdelièvre ◽  
J. Clavilier
Keyword(s):  
Carbon Monoxide ◽  
Single Crystals ◽  
Electrochemical Oxidation ◽  
Adsorbed Carbon

scholarly journals Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts. Part I: Carbon monoxide oxidation onto low index platinum single crystals

2001 ◽  
Vol 66 (11-12) ◽  
pp. 785-797 ◽  
Author(s):  
Branimir Grgur ◽  
Nenad Markovic ◽  
Chriss Lucas ◽  
Philip Ross
Keyword(s):  
Carbon Monoxide ◽  
Single Crystals ◽  
Electrochemical Oxidation ◽  
Interfacial Structure ◽  
X Ray Diffraction ◽  
Platinum Surfaces ◽  
Oxidation Of Hydrogen ◽  
Electrode Method ◽  
Platinum Single Crystals ◽  
Oxidation Of Carbon Monoxide

The electrochemical oxidation of carbon monoxide and the interfacial structure of the CO adlayer (COads) on platinum low index single crystals, Pt(111), Pt(100) and two reconstruction of Pt(110), were examined using the rotation disk electrode method in combination with the in situ surface X-ray diffraction scattering technique. The mechanism of CO oxidation is discussed on the basis of the findings that, depending on the potential, two energetic states ofCOads exist on the platinum surfaces. Thus, at lower potentials, weakly bonded states (COads,w) and at higher potentials strongly bonded states (COads,s) are formed. The mechanism of the oxidation of hydrogen-carbon monoxide mixtures is also proposed.

scholarly journals Electrochemical oxidation of carbon monoxide: From platinum single crystals to low temperature fuel cells catalysts - Part II: Electrooxidation of H2, CO and H2/CO mixtures on well characterized PtMo

2003 ◽  
Vol 68 (3) ◽  
pp. 191-205 ◽  
Author(s):  
Branimir Grgur ◽  
Nenad Markovic ◽  
Philip Ross
Keyword(s):  
Carbon Monoxide ◽  
Low Temperature ◽  
Single Crystals ◽  
Electrochemical Oxidation ◽  
Surface Concentration ◽  
Oxidation Of Co ◽  
Oxidation Of Hydrogen ◽  
Low Temperature Fuel Cells ◽  
Platinum Single Crystals ◽  
Oxidation Of Carbon Monoxide

The oxidation of hydrogen and hydrogen?carbon monoxide mixture has been investigated on well-characterized metallurgically prepared platinum?molybdenum (PtMo) alloys. It was concluded that the optimum surface concentration of molybdenum is near 23 mol.%. Based on experimentally determined parameters and simulations, the mechanism of the oxidation of CO/H2 mixtures is discussed.

The promoting effect of adsorbed carbon monoxide on the oxidation of alcohols on a gold catalyst

2011 ◽  
Vol 4 (3) ◽  
pp. 177-182 ◽  
Author(s):  
Paramaconi Rodriguez ◽  
Youngkook Kwon ◽  
Marc T. M. Koper
Keyword(s):  
Carbon Monoxide ◽  
Gold Catalyst ◽  
Promoting Effect ◽  
Oxidation Of Alcohols ◽  
Adsorbed Carbon
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