Simulation of electrochemiluminescence produced by a high-frequency square-wave potential waveform. Effects of ohmic drop and cell time constant on electrode potential, current and light emission

1995 ◽  
Vol 397 (1-2) ◽  
pp. 19-26 ◽  
Author(s):  
P. Pastore ◽  
F. Magno ◽  
M.M. Collinson ◽  
R.M. Wightman
Fuel Cells ◽  
2010 ◽  
Vol 10 (3) ◽  
pp. 384-389 ◽  
Author(s):  
L. Zheng ◽  
J. Sun ◽  
L. Xiong ◽  
R. Jin ◽  
J. Li ◽  
...  

CrystEngComm ◽  
2021 ◽  
Vol 23 (38) ◽  
pp. 6655-6660
Author(s):  
Chi Xiao ◽  
Na Tian ◽  
Wei-Ze Li ◽  
Xi-Ming Qu ◽  
Jia-Huan Du ◽  
...  

Shape transformation between high-index faceted Pt nanocrystals and low-index faceted ones have been achieved by an electrochemical square-wave potential method.


Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5722
Author(s):  
Shihang Wang ◽  
Chuang Zhang ◽  
Hang Fu ◽  
Jiao Xiang ◽  
Jianying Li ◽  
...  

Insulation fails quickly under high-frequency AC high voltage, especially bipolar square-wave voltage with a high dV/dt. It is of great significance to study the failure mechanism of epoxy casting insulation under such kind of voltage. In this paper, pin-plane epoxy casting insulation samples with air gaps were prepared, and the relation between the electrical trees under the high frequency bipolar square-wave voltage and the air gap conditions and voltage frequencies (1~20 kHz) were studied. Results indicated that, with the presence of air gaps, the electrical trees were bush-type and had a relatively slow growth rate, which was different from the fast-growing branch-type trees in the samples without air gap. The electrical tree characteristics related with the size of air gap and voltage frequency were also studied. The electrical tree grew faster under higher voltage frequency or with a smaller air gap. Results proved that discharge introduced a lot of defects for the surface layer of the epoxy resin samples and hence induced the possibility of multi-directional expansion of electrical trees. In addition, the resulting heat accumulation and unique charge transport synergistically affected the electrical tree characteristics under the high frequency bipolar square-wave voltage.


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