Thermodynamics of polymer/diluent systems for thermally induced phase separation: 2. Solid-liquid phase separation systems

Polymer ◽  
1992 ◽  
Vol 33 (5) ◽  
pp. 1036-1046 ◽  
Author(s):  
Sung Soo Kim ◽  
Douglas R. Lloyd
1985 ◽  
Vol 40 (7) ◽  
pp. 693-698 ◽  
Author(s):  
M. Woznyj ◽  
H.-D. Lüdemann

The phase diagram t-butanol/water is studied in the temperature range between 200 and 450 K at pressures up to 200 MPa. No liquid/liquid phase separation is observed in this range. The solid/liquid phase diagram reveals the presence of a stable t-butanol/dihydrate at all pressures. At the t-butanol rich side of the diagram solid mixtures with compositions t-butanol/water ~ 5 :1 and ~ 6 : 1 are observed.


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