Magnetic ordering in the system Co2-xNix TiSn studied by 119Sn-Mössbauer spectroscopy and magnetization measurements

1978 ◽  
Vol 25 (9) ◽  
pp. 661-663 ◽  
Author(s):  
E.A. Görlich ◽  
K. Łatka ◽  
A. Szytuła ◽  
D. Wagner ◽  
R. Kmieć ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Mossbauer Spectroscopy ◽  
Magnetic Ordering ◽  
119Sn Mössbauer Spectroscopy ◽  
Magnetization Measurements ◽  
Mößbauer Spectroscopy

Ternary Stannides RE3Ru4Sn13 (RE = La, Ce, Pr, Nd) – Structure, Magnetic Properties, and 119Sn Mössbauer Spectroscopy

2011 ◽  
Vol 66 (7) ◽  
pp. 664-670
Author(s):  
◽  
Christian Schwickert ◽  
Thorsten Langer ◽  
Rainer Pöttgen
Keyword(s):  
Mössbauer Spectroscopy ◽  
Mossbauer Spectroscopy ◽  
Three Dimensional ◽  
Magnetic Ordering ◽  
119Sn Mössbauer Spectroscopy ◽  
X Ray Diffraction ◽  
Temperature Dependent ◽  
Mößbauer Spectroscopy ◽  
Arc Melting ◽  
Different Types

The ternary stannides RE3Ru4Sn13 (RE = La, Ce, Pr, Nd) were obtained by arc-melting of the elements. The polycrystalline samples were characterized by powder X-ray diffraction. The structures of three compounds were refined from single-crystal diffractometer data: Yb3Rh4Sn13 type, Pm3̄n, a = 977.74(3) pm, wR2 = 0.0379, 280 F2 values for La3Ru4Sn13, a = 971.34(9) pm, wR2 = 0.0333, 274 F2 values for Ce3Ru4Sn13, a = 970.68(8) pm, wR2 = 0.0262, 272 F2 values for Nd3Ru4Sn13 with 13 variables per refinement. The structures consist of three-dimensional networks of condensed RuSn6/2 trigonal prisms with the RE (CN 16) and Sn2 (CN 12) atoms in two different types of cavities of the networks. The two crystallographically independent tin sites have been resolved by 119Sn Mössbauer spectroscopy. Temperature-dependent magnetic susceptibility measurements of Ce3Ru4Sn13 gave a reduced magnetic moment of 2.32 μB per Ce atom, indicating intermediate cerium valence. No magnetic ordering was evident down to 3 K.

In situ 119Sn Mössbauer spectroscopy study of Sn-based electrode materials

2006 ◽  
Vol 167 (1-3) ◽  
pp. 733-738 ◽  
Author(s):  
Abdelmaula Aboulaich ◽  
Florent Robert ◽  
Pierre Emmanuel Lippens ◽  
Laurent Aldon ◽  
Josette Olivier-Fourcade ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Electrode Materials ◽  
Mossbauer Spectroscopy ◽  
Spectroscopy Study ◽  
119Sn Mössbauer Spectroscopy ◽  
Mößbauer Spectroscopy

USING NEUTRON DIFFRACTION AND MÖSSBAUER SPECTROSCOPY TO STUDY MAGNETIC ORDERING IN THE R3T4Sn4 FAMILY OF COMPOUNDS

2010 ◽  
Vol 24 (01) ◽  
pp. 1-28 ◽  
Author(s):  
D. H. RYAN ◽  
J. M. CADOGAN ◽  
C. J. VOYER ◽  
M. NAPOLETANO ◽  
P. RIANI ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Intermetallic Compound ◽  
Neutron Diffraction ◽  
Mossbauer Spectroscopy ◽  
Magnetic Ordering ◽  
Mößbauer Spectroscopy ◽  
Compound Series

We review the complementary roles that 119Sn Mössbauer spectroscopy and neutron diffraction are playing in developing a complete description of magnetic ordering in the R 3 Cu 4 Sn 4 and R 3 Ag 4 Sn 4 intermetallic compound series. We show that the two techniques yield consistent pictures of the order, and in many cases both are essential to obtaining a complete description. The recent neutron diffraction work on Sm 3 Cu 4 Sn 4, Sm 3 Ag 4 Sn 4 and Gd 3 Ag 4 Sn 4 is highlighted.

Sign in / Sign up

Export Citation Format

Share Document