Thermodynamic analysis of the quasi-binary section A-Pb in the ternary system Pb-Bi-Mg

1993 ◽  
Vol 230 ◽  
pp. 77-81 ◽  
Author(s):  
Dragana Živković ◽  
Živan Živković ◽  
Jaroslav Šesták
Keyword(s):  
Ternary System ◽  
Thermodynamic Analysis ◽  
Binary Section ◽  
Quasi Binary Section

Thermodynamic analysis of the quasi-binary section A-Pb in the ternary system Pb-Bi-Mg

1993 ◽  
Vol 230 ◽  
pp. 65-75 ◽  
Author(s):  
Dragana Živković ◽  
Živan Živković ◽  
Jaroslav Šesták
Keyword(s):  
Ternary System ◽  
Thermodynamic Analysis ◽  
Binary Section ◽  
Quasi Binary Section

scholarly journals STUDY OF THE CU3AS4TE9-CRASTE3 SECTION OF THE AS2Te3-Cr2Te3-CuTe quasi-ternary system

2021 ◽  
pp. 40-44
Author(s):  
S. Ismailova
Keyword(s):  
Phase Diagram ◽  
Solid Solution ◽  
Ternary System ◽  
Solid Solutions ◽  
Room Temperature ◽  
Physicochemical Analysis ◽  
Binary Section ◽  
Quasi Binary Section ◽  
Quasi Ternary System

Chemical interactions in the system were studied by methods of physicochemical analysis (DTA, XRD, MSA, determination of density and microhardness) and its phase diagram was constructed. It was found that the phase diagram of the system is a non-quasi-binary section of the quasi-ternary system As2Te3-Cr2Te3-CuTe. At room temperature in the system of solid solutions based on Cu3As4Te9 reaches - 5 mol. % CrAsTe3. The region of the solid solution based on the CrAsTe3 compound has not been established in practice. The dependence of the microhardness and density of alloys of the Cu3As4Te9-CrAsTe3 system on the composition has been investigated.

scholarly journals Thermodynamic analysis of ternary system Ga-In-Sb

2008 ◽  
Vol 62 (3) ◽  
pp. 153-159 ◽  
Author(s):  
Lidija Gomidzelovic ◽  
Dragana Zivkovic ◽  
Ivan Mihajlovic
Keyword(s):  
General Solution ◽  
Ternary System ◽  
Temperature Interval ◽  
Thermodynamic Analysis ◽  
Interaction Parameters ◽  
Ternary Interaction ◽  
Gibbs Energies

The results of thermodynamic analysis of ternary system Ga-In-Sb are presented in these work. Thermodynamic analysis was carried out by applying general solution predicting method in sections from Ga, In and Sb corner, respectively, with following ratios 1:3, 1:1, 3:1 in the temperature interval 873 to 1673 K. Based on this, excess molar Gibbs energies and activity of all components in specified temperature interval were calculated. Also, using the obtained data and MLAB software, ternary interaction parameters for Ga-In-Sb system were determined.

Ba5Al2Ge7 und Ba7Al4Ge9: Zwei neue intermetallische Phasen mit ungewöhnlichen Al-Ge-Anionen / Ba5Al2Ge7 and Ba7Al4Ge9: Two New Intermetallic Phases with Unusual Al-Ge Anions

2007 ◽  
Vol 62 (8) ◽  
pp. 1059-1070 ◽  
Author(s):  
Marco Wendorff ◽  
Caroline Röhr
Keyword(s):  
Ternary System ◽  
Single Crystal ◽  
Structure Type ◽  
Intermetallic Phases ◽  
Crystal Data ◽  
Form Complex ◽  
Space Group ◽  
X Ray ◽  
Al Content ◽  
Binary Section

In the ternary system Ba-Al-Ge new intermetallic compounds which are lying on or close to the binary section BaAl2 -BaGe2 were synthesized from the elements and characterized on the basis of X-ray single crystal data. The Al-content x in the compounds BaAlxGe2−x forming the AlB2 structure type ranges from x = 1.4 [BaAl1.4Ge0.6 space group P6/mmm, a = 443.5(1), c = 512.4(1) pm, Z = 1, R1 = 0.0222] to the stoichiometric ordered compound BaAlGe [space group P6̅m2, a = 434.9(1), c = 513.6 pm, Z = 1, R1 = 0.0252]. In the two new Ge-rich barium intermetallics Ba5Al2Ge7 [space group C2/m, a = 859.8(4), b = 1031.5(4), c = 1847.8(6) pm, β = 103.23(3)°, Z = 4, R1 = 0.0553] and Ba7Al4Ge9 [space group Fmm2, a = 1032.7(5), b = 2559(2), c = 862.1(4) pm, Z = 4, R1 = 0.1197] complex Al/Ge polyanions are present, which consist of (1) Al/Ge-ribbons of condensed planar sixmembered rings comparable to the anions in Ba3Al2Ge2, and (2) [Ge/Al]5 clusters comparable to the anions in the tetrelides Ba3M5. The building units (1) and (2) are connected via Al-Ge bonds to form complex ribbons in the case of Ba5Al2Ge7 and sheets in the case of Ba7Al4Ge9. The electron count in the two compounds supports an interpretation of the structures according to the Zintl concept and the Wades rules. The small formal electron excess, caused by the incomplete transfer of charge from Ba towards the Al/Ge polyanions, decreases with the Ge content of the compound.

Thermodynamic analysis of phase equilibria in the Cr–Mo–B ternary system

Calphad ◽  
2010 ◽  
Vol 34 (3) ◽  
pp. 263-270 ◽  
Author(s):  
Masayuki Tojo ◽  
Tatsuya Tokunaga ◽  
Hiroshi Ohtani ◽  
Mitsuhiro Hasebe
Keyword(s):  
Ternary System ◽  
Phase Equilibria ◽  
Thermodynamic Analysis

scholarly journals Thermodynamic Analysis of Phase Equilibria in the Mn-Bi-Sb Ternary System

2014 ◽  
Vol 78 (9) ◽  
pp. 327-336 ◽  
Author(s):  
Manami Uemitsu ◽  
Masanori Enoki ◽  
Satoshi Iikubo ◽  
Hiroshi Ohtani
Keyword(s):  
Ternary System ◽  
Phase Equilibria ◽  
Thermodynamic Analysis

scholarly journals Phase relations in the CuI-SbSI-SbI3 composition range of the Cu–Sb–S–I quaternary system

2021 ◽  
Vol 23 (2) ◽  
pp. 236-244
Author(s):  
Parvin R. Mammadli ◽  
Vagif A. Gasymov ◽  
Ganira B. Dashdiyeva ◽  
Dunya M. Babanly
Keyword(s):  
Quaternary System ◽  
Composition Range ◽  
Liquidus Surface ◽  
Polymorphic Transitions ◽  
X Ray ◽  
Immiscibility Region ◽  
Binary Section ◽  
Quasi Binary Section ◽  
Polythermal Sections ◽  
Primary Crystallisation

The phase equilibria in the Cu-Sb-S-I quaternary system were studied by differential thermal analysis and X-ray phase analysis methods in the CuI-SbSI-SbI3 concentration intervals. The boundary quasi-binary section CuI-SbSI, 2 internal polythermal sections of the phase diagram, as well as, the projection of the liquidus surface were constructed. Primary crystallisation areas of phases, types, and coordinates of non- and monovariant equilibria were determined. Limited areas of solid solutions based on the SbSI (b-phase) and high-temperature modifications of the CuI (α1- and α2- phases) were revealed in the system. The formation of the α1 and α2 phases is accompanied by a decrease in the temperatures of the polymorphic transitions of CuI and the establishment of metatectic (3750C) and eutectoid (2800C) reactions. It was also shown, that the system is characterised by the presence of a wide immiscibility region that covers a significant part of theliquidus surface of the CuI and SbSI based phases 

scholarly journals Research of tнe quasi-binary section SmGe2 – LuGe2

2018 ◽  
Vol 59 (1) ◽  
pp. 83
Author(s):  
O. Kravchuk ◽  
Z. Shpyrka ◽  
N. German ◽  
V. Pavluk
Keyword(s):  
Binary Section ◽  
Quasi Binary Section
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