Prospects for solar synthesis I: A new method for singlet oxygen reactions using natural sunlight

1984 ◽  
Vol 25 (2-4) ◽  
pp. 501-509 ◽  
Author(s):  
J.E. Guillet ◽  
J. Sherren ◽  
H.M. Gharapetian ◽  
W.K. MacInnis
2012 ◽  
Vol 53 ◽  
pp. S146
Author(s):  
A. Iwasawa⁎ ◽  
Y. Matsumrua ◽  
T. Kamachi ◽  
T. Ozawa ◽  
M. Kohno

2012 ◽  
Vol 16 (12) ◽  
pp. 1244-1251 ◽  
Author(s):  
Nina A. Kuznetsova ◽  
Ekaterina N. Shevchenko ◽  
Dmitry A. Makarov ◽  
Ludmila K. Slivka ◽  
Ludmila I. Solovyova ◽  
...  

A new method of preparation and the properties (solubility, aggregation, spectralluminescent properties, singlet oxygen and photobleaching quantum yields) of non-metal 2,3,9,10,16,17,23,24-octacarboxyphthalocyanine are reported. The influence of ionization state on photophysicochemical properties of this dye is also presented.


Nature ◽  
1976 ◽  
Vol 263 (5576) ◽  
pp. 442-443 ◽  
Author(s):  
Y. LION ◽  
M. DELMELLE ◽  
A. VAN DE VORST

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1685
Author(s):  
Jayson S. Wau ◽  
Mark J. Robertson ◽  
Michael Oelgemöller

Photooxygenation reactions involving singlet oxygen (1O2) are utilized industrially as a mild and sustainable access to oxygenated products. Due to the usage of organic dyes as photosensitizers, these transformations can be successfully conducted using natural sunlight. Modern solar chemical reactors enable outdoor operations on the demonstration (multigram) to technical (multikilogram) scales and have subsequently been employed for the manufacturing of fine chemicals such as fragrances or biologically active compounds. This review will highlight examples of solar photooxygenations for the manufacturing of industrially relevant target compounds and will discuss current challenges and opportunities of this sustainable methodology.


Author(s):  
C. C. Clawson ◽  
L. W. Anderson ◽  
R. A. Good

Investigations which require electron microscope examination of a few specific areas of non-homogeneous tissues make random sampling of small blocks an inefficient and unrewarding procedure. Therefore, several investigators have devised methods which allow obtaining sample blocks for electron microscopy from region of tissue previously identified by light microscopy of present here techniques which make possible: 1) sampling tissue for electron microscopy from selected areas previously identified by light microscopy of relatively large pieces of tissue; 2) dehydration and embedding large numbers of individually identified blocks while keeping each one separate; 3) a new method of maintaining specific orientation of blocks during embedding; 4) special light microscopic staining or fluorescent procedures and electron microscopy on immediately adjacent small areas of tissue.


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