Rare earth elements in apatite and magnetite in Kiruna-type iron ores and some other iron ore types

1995 ◽  
Vol 9 (6) ◽  
pp. 489-510 ◽  
Author(s):  
Rudyard Frietsch ◽  
Jan-Anders Perdahl
2017 ◽  
Vol 6 (2) ◽  
pp. 537-546 ◽  
Author(s):  
Mohammadali Sarparandeh ◽  
Ardeshir Hezarkhani

Abstract. The use of efficient methods for data processing has always been of interest to researchers in the field of earth sciences. Pattern recognition techniques are appropriate methods for high-dimensional data such as geochemical data. Evaluation of the geochemical distribution of rare earth elements (REEs) requires the use of such methods. In particular, the multivariate nature of REE data makes them a good target for numerical analysis. The main subject of this paper is application of unsupervised pattern recognition approaches in evaluating geochemical distribution of REEs in the Kiruna type magnetite–apatite deposit of Se-Chahun. For this purpose, 42 bulk lithology samples were collected from the Se-Chahun iron ore deposit. In this study, 14 rare earth elements were measured with inductively coupled plasma mass spectrometry (ICP-MS). Pattern recognition makes it possible to evaluate the relations between the samples based on all these 14 features, simultaneously. In addition to providing easy solutions, discovery of the hidden information and relations of data samples is the advantage of these methods. Therefore, four clustering methods (unsupervised pattern recognition) – including a modified basic sequential algorithmic scheme (MBSAS), hierarchical (agglomerative) clustering, k-means clustering and self-organizing map (SOM) – were applied and results were evaluated using the silhouette criterion. Samples were clustered in four types. Finally, the results of this study were validated with geological facts and analysis results from, for example, scanning electron microscopy (SEM), X-ray diffraction (XRD), ICP-MS and optical mineralogy. The results of the k-means clustering and SOM methods have the best matches with reality, with experimental studies of samples and with field surveys. Since only the rare earth elements are used in this division, a good agreement of the results with lithology is considerable. It is concluded that the combination of the proposed methods and geological studies leads to finding some hidden information, and this approach has the best results compared to using only one of them.


2017 ◽  
Author(s):  
Mohammadali Sarparandeh ◽  
Ardeshir Hezarkhani

Abstract. The use of efficient methods for data processing has always been of interest by researchers in the field of earth science. Pattern recognition techniques are appropriate methods for high-dimensional data such as geochemical data. Evaluation of geochemical distribution of REEs needs to use such methods. Especially multivariate nature of REEs data makes it a good target for numerical analysis. The main subject of this paper is application of unsupervised pattern recognition approaches in evaluating geochemical distribution of rare earth elements (REEs) in the Kiruna type magnetite–apatite deposit of Se-Chahun. For this purpose, 42 bulk lithology samples were collected from Se-Chahun iron ore deposit. In this study, 14 rare earth elements were measured with ICP-MS. Pattern recognition makes it possible to evaluate the relations between the samples based on all these 14 features, simultaneously. In addition to providing easy solutions, discovery of the hidden information and relations of data samples is the advantage of these methods. Therefore, four clustering methods (unsupervised pattern recognition) including modified basic sequential algorithmic scheme (MBSAS), hierarchical (agglomerative), k-means and self-organizing map (SOM) were applied and results were evaluated using silhouette criterion. Samples were clustered in four types. Finally, the results of this study were validated with geological facts, and analysis results such as SEM, XRD, ICP-MS and optical mineralogy. The results of k-means and SOM have the best matches with reality, experimental studies of samples and also field surveys. Since only the rare earth elements are used in this division, a good agreement of the results with lithology is considerable. It concluded that the combination of the proposed methods and geological studies, leads to finding some hidden information and this approach has the best results compared to using only one of them.


2015 ◽  
Vol 45 (2) ◽  
pp. 193-216 ◽  
Author(s):  
Lucilia Aparecida Ramos de Oliveira ◽  
Carlos Alberto Rosière ◽  
Francisco Javier Rios ◽  
Sandra Andrade ◽  
Renato de Moraes

<p>Chemical signatures of iron oxides from dolomitic itabirite and high-grade iron ore from the Esperança deposit, located in the Quadrilátero Ferrífero, indicate that polycyclic processes involving changing of chemical and redox conditions are responsible for the iron enrichment on Cauê Formation from Minas Supergroup. Variations of Mn, Mg and Sr content in different generations of iron oxides from dolomitic itabirite, high-grade iron ore and syn-mineralization quartz-carbonate-hematite veins denote the close relationship between high-grade iron ore formation and carbonate alteration. This indicates that dolomitic itabirite is the main precursor of the iron ore in that deposit. Long-lasting percolation of hydrothermal fluids and shifts in the redox conditions have contributed to changes in the Y/Ho ratio, light/heavy rare earth elements ratio and Ce anomaly with successive iron oxide generations (martite-granular hematite), as well as lower abundance of trace elements including rare earth elements in the younger specularite generations.</p>


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