Igneous Rock Associations 28. Construction of a Venusian Greenstone Belt: A Petrological Perspective

The crustal evolution of Venus appears to be principally driven by intraplate processes that may be related to mantle upwelling as there is no physiographic (i.e. mid-ocean ridge, volcanic arc) evidence of Earth-like plate tectonics. Rocks with basaltic composition were identified at the Venera 9, 10, 13, and 14, and Vega 1 and 2 landing sites whereas the rock encountered at the Venera 8 landing site may be silicic. The Venera 14 rock is chemically indistinguishable from terrestrial olivine tholeiite but bears a strong resemblance to basalt from terrestrial Archean greenstone belts. Forward petrological modeling (i.e. fractional crystallization and partial melting) and primary melt composition calculations using the rock compositions of Venus can yield results indistinguishable from many volcanic (ultramafic, intermediate, silicic) and plutonic (tonalite, trondhjemite, granodiorite, anorthosite) rocks that typify Archean greenstone belts. Evidence of chemically precipitated (carbonate, evaporite, chert, banded-iron formation) and clastic (sandstone, shale) sedimentary rocks is scarce to absent, but their existence is dependent upon an ancient Venusian hydrosphere. Nevertheless, it appears that the volcanic–volcaniclastic–plutonic portion of terrestrial greenstone belts can be constructed from the known surface compositions of Venusian rocks and suggests that it is possible that Venus and Early Earth had parallel evolutionary tracks in the growth of proto-continental crust.

Mineralogical justification for potentiality of producing marketable hematite products

Hematite quartzites are a product of weathering of magnetite quartzites, which make up the ferruginous horizons of deposits of the Precambrian banded-iron formation. They occur all over the planet. The largest deposits are found in the iron-producing areas and basins of Central Kazakhstan, the Kursk magnetic anomaly, the Karelian-Kola region, Western Australia, Southeastern India, Brazil, the United States, and Canada. The geological and mineralogical issues of hematite quartzites as raw materials for producing concentrate and sinter ore have been studied most deeply and comprehensively for the deposits of the Kryvyi Rih basin and Central Kazakhstan. However, when developing an effective scheme for producing high-quality metallurgical raw materials, the mineralogical features of hematite ores have been taken into account insufficiently. The aim of the authors of the present work was to study the localization, structure of deposits and mineral composition of hematite quartzites as raw materials for sinter ore and concentrate production. Data from geological observations and mineralogical studies were used as source material. Proven geological, mineralogical, petrochemical methods were used. In accordance with the obtained results, the hematite quartzites are composed of ore-forming (quartz, hematite) and secondary (relict and newly formed) minerals. The total content of the hematite and quartz exceeds 90 mass %. The peculiarity of Ushkatyn III deposit ores is the high content of manganese oxides. The depth of distribution of the weathering crust composed of hematite quartzites varies from 200 to 1000 m. The hematite quartzites’ bodies are characterized by a zonal structure. Their central parts are represented by martite-micaceous hematite, micaceous hematite- martite quartzites; intermediate ones by martite quartzites; peripheral parts – by dispersed hematite-martite, kaolinite-martite-dispersed hematite quartzites. The horizons differ in the quantitative ratio of these varieties. The quantitative ratio of mineral varieties of hematite quartzites, morphology of individuals and aggregates of ore-forming and secondary minerals, their chemical composition and physical properties must be taken into account when developing the optimal technology for the production of high-quality hematite concentrate.

Hydrologic Alteration and Enhanced Microbial Reductive Dissolution of Fe(III) (hydr)oxides Under Flow Conditions in Fe(III)-Rich Rocks: Contribution to Cave-Forming Processes

Previous work demonstrated that microbial Fe(III)-reduction contributes to void formation, and potentially cave formation within Fe(III)-rich rocks, such as banded iron formation (BIF), iron ore and canga (a surficial duricrust), based on field observations and static batch cultures. Microbiological Fe(III) reduction is often limited when biogenic Fe(II) passivates further Fe(III) reduction, although subsurface groundwater flow and the export of biogenic Fe(II) could alleviate this passivation process, and thus accelerate cave formation. Given that static batch cultures are unlikely to reflect the dynamics of groundwater flow conditions in situ, we carried out comparative batch and column experiments to extend our understanding of the mass transport of iron and other solutes under flow conditions, and its effect on community structure dynamics and Fe(III)-reduction. A solution with chemistry approximating cave-associated porewater was amended with 5.0 mM lactate as a carbon source and added to columns packed with canga and inoculated with an assemblage of microorganisms associated with the interior of cave walls. Under anaerobic conditions, microbial Fe(III) reduction was enhanced in flow-through column incubations, compared to static batch incubations. During incubation, the microbial community profile in both batch culture and columns shifted from a Proteobacterial dominance to the Firmicutes, including Clostridiaceae, Peptococcaceae, and Veillonellaceae, the latter of which has not previously been shown to reduce Fe(III). The bacterial Fe(III) reduction altered the advective properties of canga-packed columns and enhanced permeability. Our results demonstrate that removing inhibitory Fe(II) via mimicking hydrologic flow of groundwater increases reduction rates and overall Fe-oxide dissolution, which in turn alters the hydrology of the Fe(III)-rich rocks. Our results also suggest that reductive weathering of Fe(III)-rich rocks such as canga, BIF, and iron ores may be more substantial than previously understood.

Channelized CO2-Rich Fluid Activity along a Subduction Interface in the Paleoproterozoic Wutai Complex, North China Craton

Greenschist facies metabasite (chlorite schist) and metasediments (banded iron formation (BIF)) in the Wutai Complex, North China Craton recorded extensive fluid activities during subduction-related metamorphism. The pervasive dolomitization in the chlorite schist and significant dolomite enrichment at the BIF–chlorite schist interface support the existence of highly channelized updip transportation of CO2-rich hydrothermal fluids. Xenotime from the chlorite schist has U concentrations of 39–254 ppm and Th concentrations of 121–2367 ppm, with U/Th ratios of 0.11–0.62, which is typical of xenotime precipitated from circulating hydrothermal fluids. SHRIMP U–Th–Pb dating of xenotime determines a fluid activity age of 1.85 ± 0.07 Ga. The metasomatic dolomite has δ13CV-PDB from −4.17‰ to −3.10‰, which is significantly lower than that of carbonates from greenschists, but similar to the fluid originated from Rayleigh fractionating decarbonation at amphibolite facies metamorphism along the regional geotherm (~15 °C/km) of the Wutai Complex. The δ18OV-SMOW values of the dolomite (12.08–13.85‰) can also correspond to this process, considering the contribution of dehydration. Based on phase equilibrium modelling, we ascertained that the hydrothermal fluid was rich in CO2, alkalis, and silica, with X(CO2) in the range of 0.24–0.28. All of these constraints suggest a channelized CO2-rich fluid activity along the sediment–basite interface in a warm Paleoproterozoic subduction zone, which allowed extensive migration and sequestration of volatiles (especially carbon species) beneath the forearc.

Orbital forcing of ice sheets during snowball Earth

The snowball Earth hypothesis—that a runaway ice-albedo feedback can cause global glaciation—seeks to explain low-latitude glacial deposits, as well as geological anomalies including the re-emergence of banded iron formation and “cap” carbonates. One of the most significant challenges to snowball Earth has been sedimentological cyclicity that has been taken to imply more climate dynamics than expected when the ocean is completely covered in ice. However, recent climate models suggest that as atmospheric CO2 accumulates, the snowball climate system becomes sensitive to orbital forcing. Here we show the presence of nearly all Milankovitch (orbital) cycles preserved in stratified banded iron formation deposited during the Sturtian snowball Earth. These results provide evidence for orbitally forced cyclicity of global ice sheets that resulted in periodic oxidation of ferrous iron. Orbital glacial advance and retreat cycles provide a simple mechanism to reconcile both the sedimentary dynamics and the enigmatic survival of multicellular life during snowball Earth.