Evaluation of propylene glycol monostearate-ethoxylated stearyl alcohol films and kinetics of cortisol release

1985 ◽  
Vol 25 (2) ◽  
pp. 199-206 ◽  
Author(s):  
Conway K.H. Chou ◽  
Ravindra C. Vasavada
1994 ◽  
Vol 49 (24) ◽  
pp. 5053-5070 ◽  
Author(s):  
T. Salmi ◽  
E. Paatero ◽  
P. Nyholm ◽  
M. Still ◽  
K. Na¨rhi

1988 ◽  
Vol 39 (1) ◽  
pp. 90-97 ◽  
Author(s):  
Khandoker M. Morshed ◽  
J.P. Nagpaul ◽  
S. Majumdar ◽  
M.K.P. Amma
Keyword(s):  

RSC Advances ◽  
2019 ◽  
Vol 9 (45) ◽  
pp. 25981-25986
Author(s):  
Viktoriia Torbina ◽  
Mikhail Salaev ◽  
Olga Vodyankina

The effect of solvent nature on conversion, product yields and reaction kinetics of selective propylene glycol oxidation with tert-butyl hydroperoxide over porous chromium terephthalate Cr-MIL-101 used as a heterogeneous catalyst is considered.


2013 ◽  
Vol 773 ◽  
pp. 316-321
Author(s):  
Xiang Feng Xiong ◽  
Chao Yin Chen ◽  
Sheng Lan Zhao ◽  
Ben Yong Han

Conjugated linoleic acid (CLA) was prepared by alkali isomerization using walnut oil as raw materials, KOH as catalyst and propylene glycol as solvent. The kinetics of alkali isomerization of linoleic acid from walnut oil converted into CLA was experimentally studied under the reaction conditions of 393~453 K,and which the initial mass ratio of propylene glycol, walnut oil and KOH was 3:2:1. The mechanism of alkali isomerization was proposed, and the mechanism model was put forward through theoretical derivation.The rate constants were determined, the mechanism model was verified,and the kinetics parameters were obtained.The results showed that alkali isomerization reaction was first order the concentration of linoleic acid, which the apparent activation energy was 67.22 kJ·mol-1 and the pre-exponential constant was 8.963×105min-1.


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