Ultrasensitive spectroscopy of ionic reactive intermediates in the gas phase performed with the first coupling of an IR FEL with an FTICR-MS

2003 ◽  
pp. 541-546
Author(s):  
Philippe Maître ◽  
Sophie Le Caër ◽  
Aude Simon ◽  
William Jones ◽  
Joël Lemaire ◽  
...  
Keyword(s):  
Gas Phase ◽  
Reactive Intermediates ◽  
Fticr Ms

scholarly journals Photoelectron spectroscopy of reactive intermediates

1988 ◽  
Vol 324 (1578) ◽  
pp. 197-207 ◽  
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Photoelectron Spectroscopy ◽  
Photoelectron Spectrum ◽  
Reactive Intermediates ◽  
Vapour Phase ◽  
Photoelectron Spectra ◽  
Triatomic Molecule ◽  
Recent Developments ◽  
Vanadium Monoxide

Recent developments in the use of photoelectron spectroscopy to study reactive intermediates in the gas phase are reviewed. The information to be derived on low-lying cationic states from such studies is illustrated by considering two diatomic molecules, NCI and PF, and one triatomic molecule, HNO. Also, the use of a transition-metal photoelectron spectrum to interpret the photoelectron spectrum of the corresponding transition-metal oxide is discussed by using the spectra of vanadium and vanadium monoxide as examples. The value of super-heating in high-temperature photoelectron spectroscopy is demonstrated by considering the vapour-phase photoelectron spectra of the monomers and dimers of sodium hydroxide.

A Strategy for Generating Naked-Metal Clusters for Gas-Phase Reactivity Studies by FTICR–MS

2003 ◽  
Vol 115 (46) ◽  
pp. 5930-5933 ◽  
Author(s):  
Colin P. G. Butcher ◽  
Adriana Dinca ◽  
Paul J. Dyson ◽  
Brian F. G. Johnson ◽  
Patrick R. R. Langridge-Smith ◽  
...  
Keyword(s):  
Gas Phase ◽  
Metal Clusters ◽  
Fticr Ms

A Strategy for Generating Naked-Metal Clusters for Gas-Phase Reactivity Studies by FTICR–MS

2003 ◽  
Vol 42 (46) ◽  
pp. 5752-5755 ◽  
Author(s):  
Colin P. G. Butcher ◽  
Adriana Dinca ◽  
Paul J. Dyson ◽  
Brian F. G. Johnson ◽  
Patrick R. R. Langridge-Smith ◽  
...  
Keyword(s):  
Gas Phase ◽  
Metal Clusters ◽  
Fticr Ms

Hydrolytische Bildung von Perchlorsiloxanen / Formation of Chlorosiloxanes by Hydrolysis

1999 ◽  
Vol 54 (5) ◽  
pp. 577-582 ◽  
Author(s):  
Heike Quellhorst ◽  
Andreas Wilkening ◽  
Nicola Söger ◽  
Michael Binnewies
Keyword(s):  
Mass Spectrometry ◽  
Gas Phase ◽  
Reactive Intermediates ◽  
Reaction Products ◽  
Condensation Reactions ◽  
Intramolecular Condensation ◽  
Hydrolysis Reactions

During the reaction of Si2OCl6 with H2O in the gas phase the intermediate Si2OCl5OH has been observed by mass-spectrometry. Reactive intermediates like this are responsible for the formation of higher chlorosilanes by slow hydrolysis reactions of chlorosilanes and -siloxanes. Reaction products of inter- and intramolecular condensation reactions have been observed by GC-MS-methods.

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