Transition Metal Nanoparticles as Catalyst in Hydrogen Generation from the Boron-Based Hydrogen Storage Materials

Author(s):  
Saim Özkar
2008 ◽  
Vol 465 (1-2) ◽  
pp. 527-533 ◽  
Author(s):  
Huaiyu Shao ◽  
Tong Liu ◽  
Yuntao Wang ◽  
Hairuo Xu ◽  
Xingguo Li

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Zhang-Hui Lu ◽  
Qilu Yao ◽  
Zhujun Zhang ◽  
Yuwen Yang ◽  
Xiangshu Chen

Ammonia borane (denoted as AB, NH3BH3) and hydrazine borane (denoted as HB, N2H4BH3), having hydrogen content as high as 19.6 wt% and 15.4 wt%, respectively, have been considered as promising hydrogen storage materials. Particularly, the AB and HB hydrolytic dehydrogenation system can ideally release 7.8 wt% and 12.2 wt% hydrogen of the starting materials, respectively, showing their high potential for chemical hydrogen storage. A variety of nanocatalysts have been prepared for catalytic dehydrogenation from aqueous or methanolic solution of AB and HB. In this review, we survey the research progresses in nanocatalysts for hydrogen generation from the hydrolysis or methanolysis of NH3BH3and N2H4BH3.


Sign in / Sign up

Export Citation Format

Share Document