Highly efficient and selective oxidation of various substrates under mild conditions using a lanthanum-containing polyoxometalate as catalyst

2013 ◽  
Vol 453 ◽  
pp. 188-194 ◽  
Author(s):  
Shen Zhao ◽  
Yueqing Jia ◽  
Yu-Fei Song
RSC Advances ◽  
2016 ◽  
Vol 6 (101) ◽  
pp. 99096-99104 ◽  
Author(s):  
H. Ramezanalizadeh ◽  
F. Manteghi

In this work, a novel metal–organic framework based composite with BiFeO3 noted as MOF/BiFeO3 has been synthesized and successfully employed as a highly efficient heterogeneous and recoverable catalyst for oxidation of alcohols under mild conditions.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4294
Author(s):  
Ana P. C. Ribeiro ◽  
Inês A. S. Matias ◽  
Poorya Zargaran ◽  
A. Stephen K. Hashmi ◽  
Luísa M. D. R. S. Martins

The highly efficient eco-friendly synthesis of acetic acid (40% yield) directly from ethane is achieved by the unprecedented use of N-heterocyclic carbene (NHC) and N-heterocyclic oxo-carbene (NHOC) gold(I) catalysts in mild conditions. This is a selective and promising protocol to generate directly acetic acid from ethane, in comparison with the two most used methods: (i) the three-step, capital- and energy-intensive process based on the high-temperature conversion of methane to acetic acid; (ii) the current industrial methanol carbonylation processes, based in iridium and expensive rhodium catalysts. Green metrics determinations highlight the environmental advantages of the new ethane oxidation procedure. Comparison with previous reported published catalysts is performed to highlight the features of this remarkable protocol.


2018 ◽  
Vol 5 (3) ◽  
pp. 723-731 ◽  
Author(s):  
Xiaoling Lin ◽  
Beibei Liu ◽  
Hui Huang ◽  
Chunfeng Shi ◽  
Yang Liu ◽  
...  

ZnS-N/C derived from Zn-based chiral MOFs exhibits excellent photocatalytic activity for the selective oxidation of cis-cyclooctene under mild conditions.


Author(s):  
Xiaojiao Cai ◽  
Siyuan Fang ◽  
Yun Hang Hu

Direct and highly efficient methane conversion to methanol under mild conditions is achieved via photocatalysis over Au–Pd/TiO2.


2016 ◽  
Vol 52 (70) ◽  
pp. 10625-10628 ◽  
Author(s):  
R. J. Maya ◽  
Jubi John ◽  
R. Luxmi Varma

A highly efficient, green and recyclable heterogeneous bentonite–gold nanohybrid catalyst was developed for the selective oxidation of silanes.


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