Preparing polymer brushes on polytetrafluoroethylene films by free radical polymerization

2006 ◽  
Vol 253 (2) ◽  
pp. 983-988 ◽  
Author(s):  
Wei Sun ◽  
Yiwang Chen ◽  
Qilan Deng ◽  
Lie Chen ◽  
Lang Zhou
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Free Radical Polymerization

Preparation of End-Grafted Polymer Brushes by Nitroxide-Mediated Free Radical Polymerization of Vaporized Vinyl Monomers

Langmuir ◽  
2005 ◽  
Vol 21 (21) ◽  
pp. 9562-9567 ◽  
Author(s):  
Jun Li ◽  
Xiaoru Chen ◽  
Ying-Chih Chang
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Free Radical Polymerization ◽  
Vinyl Monomers ◽  
Grafted Polymer

Controlled Synthesis of Polymer Brushes by “Living” Free Radical Polymerization Techniques

1999 ◽  
Vol 32 (5) ◽  
pp. 1424-1431 ◽  
Author(s):  
Marc Husseman ◽  
Eva E. Malmström ◽  
Molly McNamara ◽  
Mathew Mate ◽  
David Mecerreyes ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Free Radical Polymerization ◽  
Controlled Synthesis ◽  
Living Free Radical Polymerization

scholarly journals Synthesis of Polymer Brushes by Surface-Initiated Controlled/Living Free Radical Polymerization Techniques

2020 ◽  
Author(s):  
Kübra HÜKÜM ÖZKAN ◽  
Esma MUTLUTÜRK ◽  
Tugba DEMİR ÇALIŞKAN ◽  
Tuncer ÇAYKARA
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Free Radical Polymerization ◽  
Living Free Radical Polymerization

Preparing polymer brushes on poly(vinylidene fluoride) films by free radical polymerization

2006 ◽  
Vol 101 (2) ◽  
pp. 857-862 ◽  
Author(s):  
Wei Sun ◽  
Yiwang Chen ◽  
Lang Zhou ◽  
Xiaohui He
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Vinylidene Fluoride ◽  
Free Radical Polymerization ◽  
Poly Vinylidene Fluoride

Fabrication of Stimulus-Responsive Polymeric Nanostructures by Proximal Probes

2002 ◽  
Vol 735 ◽  
Author(s):  
Sang-Jung Ahn ◽  
Woo-Kjung Lee ◽  
Stefan Zauscher
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Polymer Brush ◽  
Free Radical Polymerization ◽  
Surface Initiated Polymerization ◽  
Stimulus Responsive ◽  
Responsive Polymer ◽  
Assembled Monolayers ◽  
Detection Of Biomolecules

ABSTRACTThe triggered control of interfacial properties on the nanometer scale holds significant promise for actuation in bio-nanotechnology applications where polymeric actuators may manipulate the transport, separation, and detection of biomolecules. To fabricate patterned, stimulus-responsive polymer brushes we have developed several methods that combine surface initiated polymerization (SIP) with dip-pen nanolithography (DPN). Surface-confined, stimulus-responsive polymer brush nanopatterns were fabricated by amplification of DPN patterned, self-assembled monolayers of 16-mercaptohexadecanoic acid on gold surfaces by SIP of N-isopropylacrylamide (NIPAAm). While free radical polymerization yielded only short polymer brushes (DP<50), atom transfer free radical polymerization (ATRP) produced thick, uniform polymer brushes. For free radical polymerization the thickness of the polymer brush layer is a function of the lateral feature size and the initiator density and is maximal at pattern boundaries.

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of

Critically evaluated rate coefficients for free-radical polymerization, 3. Propagation rate coefficients for alkyl methacrylates

2000 ◽  
Vol 201 (12) ◽  
pp. 1355-1364 ◽  
Author(s):  
Sabine Beuermann ◽  
Michael Buback ◽  
Thomas P. Davis ◽  
Robert G. Gilbert ◽  
Robin A. Hutchinson ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Propagation Rate ◽  
Rate Coefficients ◽  
Alkyl Methacrylates

Oxygen-Initiated Free-Radical Polymerization of Alkyl Acrylates at High Temperatures

2021 ◽  
Author(s):  
Shi Liu ◽  
Lauren Chua ◽  
Ahmad Arabi Shamsabadi ◽  
Patrick Corcoran ◽  
Abhirup Patra ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
High Temperatures ◽  
Free Radical Polymerization ◽  
Alkyl Acrylates
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