surface initiated polymerization
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2021 ◽  
Vol 7 (13) ◽  
pp. eabf3804 ◽  
Author(s):  
Seo Woo Song ◽  
Sumin Lee ◽  
Jun Kyu Choe ◽  
Na-Hyang Kim ◽  
Junwon Kang ◽  
...  

Pen drawing is a method that allows simple, inexpensive, and intuitive two-dimensional (2D) fabrication. To integrate such advantages of pen drawing in fabricating 3D objects, we developed a 3D fabrication technology that can directly transform pen-drawn 2D precursors into 3D geometries. 2D-to-3D transformation of pen drawings is facilitated by surface tension–driven capillary peeling and floating of dried ink film when the drawing is dipped into an aqueous monomer solution. Selective control of the floating and anchoring parts of a 2D precursor allowed the 2D drawing to transform into the designed 3D structure. The transformed 3D geometry can then be fixed by structural reinforcement using surface-initiated polymerization. By transforming simple pen-drawn 2D structures into complex 3D structures, our approach enables freestyle rapid prototyping via pen drawing, as well as mass production of 3D objects via roll-to-roll processing.


2021 ◽  
Author(s):  
Tzu-Yu Kuo ◽  
Yi-Chang Chung

Inspired by mussels, dopamine with catechol and amino groups in the molecular structure has been broadly studied for its universal attachment, biocompatibility and ease of use. Dopamine is known to...


Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 746
Author(s):  
Yu Huang ◽  
Xiaogang Xue ◽  
Kaiqiao Fu

In this paper, a microparticle system consisting of cationic polyacrylamide (CPAM) and anionic spherical polyelectrolyte brushes (ASPB) is proposed to improve the retention of pulp suspension containing bleached reed kraft pulp and precipitated calcium carbonate (PCC). We first describe the preparation of ASPB. The ASPB, consisting of a carbon sphere (CS) core and a shell of sodium polystyrene sulfonate (PSSNa) brushes, was synthesized by surface-initiated polymerization. The structure and morphology of ASPB were characterized by Fourier-transform infrared spectrometry (FTIR), field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Then, flocculation and retention of pulp suspension by a CPAM/ASPB dual-component system were examined. Our results indicate that more highly effective flocculation and higher retention efficiency could be achieved simultaneously by a CPAM/ASPB dual-component system when compared to the conventional microparticle system. Bridging flocculation and electrostatic attraction might be the main flocculation mechanism for CPAM/ASPB systems.


Talanta ◽  
2020 ◽  
Vol 209 ◽  
pp. 120525 ◽  
Author(s):  
Huiliang Geng ◽  
Jie Jing ◽  
Feifang Zhang ◽  
Feng Zhang ◽  
Bingcheng Yang

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