Preparing polymer brushes on poly(vinylidene fluoride) films by free radical polymerization

2006 ◽  
Vol 101 (2) ◽  
pp. 857-862 ◽  
Author(s):  
Wei Sun ◽  
Yiwang Chen ◽  
Lang Zhou ◽  
Xiaohui He
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Vinylidene Fluoride ◽  
Free Radical Polymerization ◽  
Poly Vinylidene Fluoride

Preparing polymer brushes on polytetrafluoroethylene films by free radical polymerization

2006 ◽  
Vol 253 (2) ◽  
pp. 983-988 ◽  
Author(s):  
Wei Sun ◽  
Yiwang Chen ◽  
Qilan Deng ◽  
Lie Chen ◽  
Lang Zhou
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Free Radical Polymerization

Preparation of End-Grafted Polymer Brushes by Nitroxide-Mediated Free Radical Polymerization of Vaporized Vinyl Monomers

Langmuir ◽  
2005 ◽  
Vol 21 (21) ◽  
pp. 9562-9567 ◽  
Author(s):  
Jun Li ◽  
Xiaoru Chen ◽  
Ying-Chih Chang
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Free Radical Polymerization ◽  
Vinyl Monomers ◽  
Grafted Polymer

Controlled Synthesis of Polymer Brushes by “Living” Free Radical Polymerization Techniques

1999 ◽  
Vol 32 (5) ◽  
pp. 1424-1431 ◽  
Author(s):  
Marc Husseman ◽  
Eva E. Malmström ◽  
Molly McNamara ◽  
Mathew Mate ◽  
David Mecerreyes ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Free Radical Polymerization ◽  
Controlled Synthesis ◽  
Living Free Radical Polymerization

Modification of Poly(vinylidene Fluoride) by Grafting of Functional Monomer 3-(Trimethoxysilyl)propyl Methacrylate

2011 ◽  
Vol 221 ◽  
pp. 32-36 ◽  
Author(s):  
Li Na Liu ◽  
Ying Bo Chen ◽  
Yu Feng Zhang
Keyword(s):  
Mechanical Property ◽  
Free Radical ◽  
Radical Polymerization ◽  
1H Nmr ◽  
Vinylidene Fluoride ◽  
Functional Monomer ◽  
Propyl Methacrylate ◽  
Modified Polymer ◽  
Poly Vinylidene Fluoride ◽  
Pure Pvdf

3-(trimethoxysilyl)propyl methacrylate was grafted into alkali treated poly(vinylidene fluoride) (PVDF) using free radical polymerization. 1H NMR, IR and DSC spectra of the modified polymer showed that double bonds were produced on PVDF and that 3-(trimethoxysilyl)propyl methacrylate was successfully grafted to PVDF. The membranes prepared using the grafted PVDF showed higher flux and better mechanical property than the pure PVDF membranes.

scholarly journals Synthesis of Polymer Brushes by Surface-Initiated Controlled/Living Free Radical Polymerization Techniques

2020 ◽  
Author(s):  
Kübra HÜKÜM ÖZKAN ◽  
Esma MUTLUTÜRK ◽  
Tugba DEMİR ÇALIŞKAN ◽  
Tuncer ÇAYKARA
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Free Radical Polymerization ◽  
Living Free Radical Polymerization

Fabrication of Stimulus-Responsive Polymeric Nanostructures by Proximal Probes

2002 ◽  
Vol 735 ◽  
Author(s):  
Sang-Jung Ahn ◽  
Woo-Kjung Lee ◽  
Stefan Zauscher
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Polymer Brushes ◽  
Polymer Brush ◽  
Free Radical Polymerization ◽  
Surface Initiated Polymerization ◽  
Stimulus Responsive ◽  
Responsive Polymer ◽  
Assembled Monolayers ◽  
Detection Of Biomolecules

ABSTRACTThe triggered control of interfacial properties on the nanometer scale holds significant promise for actuation in bio-nanotechnology applications where polymeric actuators may manipulate the transport, separation, and detection of biomolecules. To fabricate patterned, stimulus-responsive polymer brushes we have developed several methods that combine surface initiated polymerization (SIP) with dip-pen nanolithography (DPN). Surface-confined, stimulus-responsive polymer brush nanopatterns were fabricated by amplification of DPN patterned, self-assembled monolayers of 16-mercaptohexadecanoic acid on gold surfaces by SIP of N-isopropylacrylamide (NIPAAm). While free radical polymerization yielded only short polymer brushes (DP<50), atom transfer free radical polymerization (ATRP) produced thick, uniform polymer brushes. For free radical polymerization the thickness of the polymer brush layer is a function of the lateral feature size and the initiator density and is maximal at pattern boundaries.

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of
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