Ru/TiO2 catalyst for selective hydrogenation of benzene: Effect of surface hydroxyl groups and spillover hydrogen

2020 ◽  
Vol 525 ◽  
pp. 146627 ◽  
Author(s):  
Yingying Zhan ◽  
Chuang Zhou ◽  
Fan Jin ◽  
Chongqi Chen ◽  
Lilong Jiang
1995 ◽  
Vol 267 ◽  
pp. 159-167 ◽  
Author(s):  
T. Takei ◽  
T. Konishi ◽  
M. Fuji ◽  
T. Watanabe ◽  
M. Chikazawa

2018 ◽  
Vol 112 (20) ◽  
pp. 201903 ◽  
Author(s):  
Michal Marszewski ◽  
Danielle Butts ◽  
Esther Lan ◽  
Yan Yan ◽  
Sophia C. King ◽  
...  

2012 ◽  
Vol 445-446 ◽  
pp. 351-358 ◽  
Author(s):  
Hai-Jun Jiang ◽  
Hong-Bin Jiang ◽  
De-Ming Zhu ◽  
Xue-Li Zheng ◽  
Hai-Yan Fu ◽  
...  

1985 ◽  
Vol 50 (6) ◽  
pp. 1268-1273 ◽  
Author(s):  
Zdeněk Vít

The effect of surface dehydration on the acidity of silica-alumina and cobalt-molybdenum-alumina catalysts has been studied and compared with alumina. The catalysts were characterized by surface hydroxyl groups concentrations, acid sites concentrations and by catalytic activities in paraldehyde depolymerisation and cumene cracking. It was found that the acidity of alumina and cobalt-molybdenum-alumina catalysts increases significantly with surface dehydration and attains maximum after activation at 500-550 °C. Silica-alumina is strongly acidic even in the hydrated state, the acidity being formed already at relatively low temperature around 100 °C.


2009 ◽  
Vol 66 ◽  
pp. 277-279 ◽  
Author(s):  
Yuan Lu Xiong ◽  
Qiang Shen ◽  
Fei Chen ◽  
Jin Zheng ◽  
Lian Meng Zhang

SR/Al2O3 composites were fabricated from different heat treatment temperatures of alumina. The results show that the relative density is over 94% and flexural strength is 66.5MPa when silicone content is 33wt.%. The flexural strength of the obtained SR/Al2O3 composites is decreased when increasing the heat treatment temperature of sandy alumina, indicating that the surface hydroxyl groups directly influence the flexural strength of SR/Al2O3 composites.


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