Kinetics of reaction of benzyl chloride with sodium acetate using tetrahexylammonium chloride as a phase-transfer catalyst

2003 ◽  
Vol 87 (1-4) ◽  
pp. 179-186
Author(s):  
Sang-Wook Park ◽  
Tae-Young Kim ◽  
Dae-Won Park ◽  
Jae-Wook Lee
Keyword(s):  
Sodium Acetate ◽  
Benzyl Chloride ◽  
Phase Transfer ◽  
Phase Transfer Catalyst ◽  
Kinetics Of Reaction ◽  
Kinetics Of

A Green and Highly Efficient Protocol for Hydrolysis of Substituted Benzyl Chloride Using Ionic Liquid [bmim]BF4 as Phase-Transfer Catalyst

2010 ◽  
Vol 113-116 ◽  
pp. 1990-1992 ◽  
Author(s):  
Yong Zhang ◽  
Hong Jun Zang ◽  
Bo Wen Cheng
Keyword(s):  
Ionic Liquid ◽  
Aqueous Solutions ◽  
Benzyl Alcohol ◽  
Alkaline Hydrolysis ◽  
Benzyl Chloride ◽  
Phase Transfer ◽  
Phase Transfer Catalyst ◽  
Present Procedure ◽  
Hydrolysis Of ◽  
By Products

Alkaline hydrolysis of substituted benzyl chloride (BzCl) in ionic liquid [bmim]BF4 is investigated. The presence of the [bmim]BF4, increased the solubility of substituted BzCl in aqueous solutions and increased the selectivity toward the formation of benzyl alcohol. The main advantages of the present procedure are shorter time, higher yields, benignancy to environment and no by-products.

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